scholarly journals Overcoming the Interfacial Limitations Imposed by the Solid–Solid Interface in Solid‐State Batteries Using Ionic Liquid‐Based Interlayers

Small ◽  
2020 ◽  
Vol 16 (14) ◽  
pp. 2000279 ◽  
Author(s):  
Syed Atif Pervez ◽  
Guktae Kim ◽  
Bhaghavathi P. Vinayan ◽  
Musa A. Cambaz ◽  
Matthias Kuenzel ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Solid Interface ◽  
Solid State Batteries

scholarly journals Solid‐State Batteries: Overcoming the Interfacial Limitations Imposed by the Solid–Solid Interface in Solid‐State Batteries Using Ionic Liquid‐Based Interlayers (Small 14/2020)

Small ◽  
2020 ◽  
Vol 16 (14) ◽  
pp. 2070078
Author(s):  
Syed Atif Pervez ◽  
Guktae Kim ◽  
Bhaghavathi P. Vinayan ◽  
Musa A. Cambaz ◽  
Matthias Kuenzel ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Solid Interface ◽  
Solid State Batteries

scholarly journals The Origins of Ion Conductivity in MOF-Ionic Liquids Hybrid Solid Electrolytes

2021 ◽  
Vol 9 ◽  
Author(s):  
Roman Zettl ◽  
Ilie Hanzu
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Rational Design ◽  
Metal Organic Framework ◽  
Active Material ◽  
Metallic Lithium ◽  
Solid State Batteries ◽  
Metal Organic ◽  
Quantum Step ◽  
Ion Conductors

Fast Li+ solid ion conductors are a key component of all-solid-state batteries, a technology currently under development. The possible use of metallic lithium as active material in solid-state batteries warrants a quantum step improvement of battery specific energy, enabling further electric vehicles application. Hereby, we report the synthesis and ion conduction properties of a new solid hybrid electrolyte based on the MIL-121 metal organic framework (MOF) structure. After an ion exchange procedure that introduces Li+ in the structure, a known quantity of a soaking electrolyte is incorporated. The soaking electrolyte is based on the EMIM-TFSI ionic liquid, thus we can classify our formulation as a MOF–ionic liquid hybrid solid electrolyte. Electrical conductivity is investigated by impedance spectroscopy and preliminary studies of ion dynamics are conducted by 7Li NMR. The field of MOF-based ion conductors remains in incipient stages of research. Our report paves the way towards the rational design of new solid-state ion conductors.

Understanding the effects of chemical reactions at the cathode–electrolyte interface in sulfide based all-solid-state batteries

2019 ◽  
Vol 7 (40) ◽  
pp. 22967-22976 ◽  
Author(s):  
Sung-Kyun Jung ◽  
Hyeokjo Gwon ◽  
Seok-Soo Lee ◽  
Hyunseok Kim ◽  
Jae Cheol Lee ◽  
...  
Keyword(s):  
Solid State ◽  
Mechanical Behavior ◽  
Chemical Reactions ◽  
Paradigm Shift ◽  
Interfacial Phenomena ◽  
Solid Interface ◽  
Electrolyte Interface ◽  
Solid State Batteries ◽  
All Solid State Batteries

Driven by a paradigm shift from conventional liquid-based systems to all-solid-state batteries (ASSBs), the chemo-mechanical behavior of the solid–solid interface is of growing importance for understanding the intricate interfacial phenomena of ASSBs.

SOLID STATE BATTERIES WITH CONDUCTING POLYMERS

1983 ◽  
Vol 44 (C3) ◽  
pp. C3-567-C3-572 ◽  
Author(s):  
F. Bénière ◽  
D. Boils ◽  
H. Cánepa ◽  
J. Franco ◽  
A. Le Corre ◽  
...  
Keyword(s):  
Solid State ◽  
Conducting Polymers ◽  
Solid State Batteries

Development of Solid Electrolytes for All-Solid-State Batteries

2019 ◽  
Vol 92 (11) ◽  
pp. 430-434
Author(s):  
Akitoshi HAYASHI ◽  
Atsushi SAKUDA ◽  
Masahiro TATSUMISAGO
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

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