Homogeneous Ni(I)tetra Sulfonated Phthalocyanine Electrocatalyst Generated at Low Overpotential Clubbed with a Wet‐Scrubbing Column for High Efficiency NO Reduction to NH 3

2021 ◽  
Vol 6 (43) ◽  
pp. 11980-11984
Author(s):  
G. Muthuraman ◽  
P. Silambarasan ◽  
I.‐S. Moon
2019 ◽  
Vol 12 (9) ◽  
pp. 2842-2848 ◽  
Author(s):  
Baowen Zhou ◽  
Xianghua Kong ◽  
Srinivas Vanka ◽  
Shaobo Cheng ◽  
Nick Pant ◽  
...  

A unique GaN:Sn nanoarchitecture is integrated on planar silicon to demonstrate an energetically favorable reaction path for aqueous photoelectrochemical CO2 reduction towards formic acid with high efficiency at low overpotential.


Nukleonika ◽  
2021 ◽  
Vol 66 (4) ◽  
pp. 227-231
Author(s):  
Andrzej Pawelec ◽  
Andrzej G. Chmielewski ◽  
Yongxia Sun ◽  
Sylwester Bułka ◽  
Toms Torims ◽  
...  

Abstract Operation of marine diesel engines causes significant emission of sulphur and nitrogen oxides. It was noticed worldwide and the regulations concerning harmful emissions were introduced. There were several solutions elaborated; however, emission control for both SOx and NOx requires two distinctive processes realized in separated devices, which is problematic due to limited space on ship board and high overall costs. Therefore, the electron beam flue gas treatment (EBFGT) process was adopted to ensure the abatement of the problem of marine diesel off-gases. This novel solution combines two main processes: first the flue gas is irradiated with electron beam where NO and SO2 are oxidized; the second stage is wet scrubbing to remove both pollutants with high efficiency. Laboratory tests showed that this process could be effectively applied to remove SO2 and NOx from diesel engine off-gases. Different compositions of absorbing solution with three different oxidants (NaClO, NaClO2 and NaClO3) were tested. The highest NOx removal efficiency (>96%) was obtained when seawater-NaClO2-NaOH was used as scrubber solution at 10.9 kGy dose. The process was further tested in real maritime conditions at Riga shipyard, Latvia. More than 45% NOx was removed at a 5.5 kGy dose, corresponding to 4800 Nm3/h off-gases arising from ship emission. The operation of the plant was the first case of examination of the hybrid electron beam technology in real conditions. Taking into account the experiment conditions, good agreement was obtained with laboratory tests. The results obtained in Riga shipyard provided valuable information for the application of this technology for control of large cargo ship emission.


Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3301
Author(s):  
Moazzam Ali ◽  
Ijaz Hussain ◽  
Irfan Mehmud ◽  
Muhammad Umair ◽  
Sukai Hu ◽  
...  

Nitrogen and sulpher oxides (NOx, SOx) have become a global issue in recent years due to the fastest industrialization and urbanization. Numerous techniques are used to treat the harmful exhaust emissions, including dry, traditional wet and hybrid wet-scrubbing techniques. However, several difficulties, including high-energy requirement, limited scrubbing-liquid regeneration, formation of secondary pollutants and low efficiency, limit their industrial utilization. Regardless, the hybrid wet-scrubbing technology is gaining popularity due to low-costs, less-energy consumption and high-efficiency removal of air pollutants. The removal/reduction of NOx and SOx from the atmosphere has been the subject of several reviews in recent years. The goal of this review article is to help scientists grasp the fundamental ideas and requirements before using it commercially. This review paper emphasizes the use of green and electron-rich donors, new breakthroughs, reducing GHG emissions, and improved NOx and SOx removal catalytic systems, including selective/non-catalytic reduction (SCR/SNCR) and other techniques (functionalization by magnetic nanoparticles; NP, etc.,). It also explains that various wet-scrubbing techniques, synthesis of solid iron-oxide such as magnetic (Fe3O4) NP are receiving more interest from researchers due to the wide range of its application in numerous fields. In addition, EDTA coating on Fe3O4 NP is widely used due to its high stability over a wide pH range and solid catalytic systems. As a result, the Fe3O4@EDTA-Fe catalyst is projected to be an optimal catalyst in terms of stability, synergistic efficiency, and reusability. Finally, this review paper discusses the current of a heterogeneous catalytic system for environmental remedies and sustainable approaches.


2008 ◽  
Vol 2 (1) ◽  
pp. 100-105 ◽  
Author(s):  
A. Biswas ◽  
B. Rajmohan ◽  
C.R. Mohanty ◽  
B.C. Meikap

Removal of fly ash using wet scrubbers is widely used in the small and medium scale industries. Among the wet scrubbing methods, spray column falls into the simplest type category for its simple construction and various advantages. A novel pilot plant wet scrubber has been conceived, designed and fabricated. This paper distinctly focuses on the detailed design and fabrication of the ejector, which has been used to prepare fly ash-air mixture in the laboratory. A detail experimental investigation has been carried out to characterize the system. Studies indicate very encouraging result. The size analysis of the fly ash sample along with efficiency of fly ash removal in the wet scrubber has critically been examined. It has been found that the present system yielded mentionable high efficiency for the scrubbing of fly ash. In most of the cases, the efficiency lies between 70.% and 90.%. The maximum efficiency obtained is above 90 %.


2009 ◽  
Vol 14 (3) ◽  
pp. 158-163
Author(s):  
Mun-Sup Lim ◽  
Won Yang ◽  
Young-Nam Chun
Keyword(s):  

2005 ◽  
Vol 2005.15 (0) ◽  
pp. 235-237
Author(s):  
Shinji KAMBARA ◽  
Yuta KUMANO ◽  
Hiroshi MORITOMI ◽  
Ken Yukimura

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5708
Author(s):  
Nanli Mou ◽  
Bing Tang ◽  
Jingzhou Li ◽  
Yaqiang Zhang ◽  
Hongxing Dong ◽  
...  

Metamaterial absorbers (MMAs) with dynamic tuning features have attracted great attention recently, but most realizations to date have suffered from a decay in absorptivity as the working frequency shifts. Here, thermally tunable multi-band and ultra-broadband MMAs based on vanadium dioxide (VO2) are proposed, with nearly no reduction in absorption during the tuning process. Simulations demonstrated that the proposed design can be switched between two independently designable multi-band frequency ranges, with the absorptivity being maintained above 99.8%. Moreover, via designing multiple adjacent absorption spectra, an ultra-broadband switchable MMA that maintains high absorptivity during the tuning process is also demonstrated. Raising the ambient temperature from 298 K to 358 K, the broadband absorptive range shifts from 1.194–2.325 THz to 0.398–1.356 THz, while the absorptivity remains above 90%. This method has potential for THz communication, smart filtering, detecting, imaging, and so forth.


2019 ◽  
Vol 7 (16) ◽  
pp. 9877-9889 ◽  
Author(s):  
Xi Cao ◽  
Emily Johnson ◽  
Manashi Nath

(Co0.21Ni0.25Cu0.54)3Se2 has been identified as high-efficiency OER electrocatalyst with a low overpotential of 272 mV at 10 mA cm−2.


2019 ◽  
Vol 7 (3) ◽  
pp. 1800741 ◽  
Author(s):  
Ronghui Que ◽  
Gang Ji ◽  
Daoshuang Liu ◽  
Maolin Li ◽  
Xiuhua Wang ◽  
...  

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