In‐Situ Upgrading of Coal Pyrolysis Tar with Steam Catalytic Cracking over Ni/Al 2 O 3 Catalysts

2020 ◽  
Vol 5 (16) ◽  
pp. 4905-4912 ◽  
Author(s):  
Siqian Cao ◽  
Dechao Wang ◽  
Mingyi Wang ◽  
Jialong Zhu ◽  
Lijun Jin ◽  
...  
2018 ◽  
Vol 177 ◽  
pp. 119-128 ◽  
Author(s):  
Mingyi Wang ◽  
Lijun Jin ◽  
Yang Li ◽  
Jiannan Lv ◽  
Baoyong Wei ◽  
...  

2017 ◽  
Vol 31 (9) ◽  
pp. 9356-9362 ◽  
Author(s):  
Mingyi Wang ◽  
Lijun Jin ◽  
Yang Li ◽  
Jiaofei Wang ◽  
Xiaoyu Yang ◽  
...  

2014 ◽  
Vol 28 (8) ◽  
pp. 4934-4941 ◽  
Author(s):  
Jiangze Han ◽  
Xiaoxing Liu ◽  
Junrong Yue ◽  
Bingfeng Xi ◽  
Shiqiu Gao ◽  
...  

Fuel ◽  
2019 ◽  
Vol 250 ◽  
pp. 203-210 ◽  
Author(s):  
Mingyi Wang ◽  
Lijun Jin ◽  
Haibin Zhao ◽  
Xiaoyu Yang ◽  
Yang Li ◽  
...  

2016 ◽  
Vol 147 ◽  
pp. 41-46 ◽  
Author(s):  
Lijun Jin ◽  
Xiaoyu Bai ◽  
Yang Li ◽  
Chan Dong ◽  
Haoquan Hu ◽  
...  

2014 ◽  
Vol 2014 ◽  
pp. 1-6
Author(s):  
Yulong Wang ◽  
Ruifang Zhao ◽  
Chun Zhang ◽  
Guanlong Li ◽  
Jing Zhang ◽  
...  

The catalytic cracking method of PAHs for the pyrolysis gaseous products is proposed to control their pollution to the environment. In this study, the Py-GC-MS is used to investigate in situ the catalytic effect of CaO and Fe2O3on the 16 PAHs from Pingshuo coal pyrolysis under different catalytic temperatures and catalyst particle sizes. The results demonstrate that Fe2O3is effective than that of CaO for catalytic cracking of 16 PAHs and that their catalytic temperature corresponding to the maximum PAHs cracking rates is different. The PAHs cracking rate is up to 60.59% for Fe2O3at 600°C and is 52.88% at 700°C for CaO. The catalytic temperature and particle size of the catalysts have a significant effect on PAHs cracking rate and CaO will lose the capability of decreasing 16 PAHs when the temperature is higher than 900°C. The possible cracking process of 16 PAHs is deduced by elaborately analyzing the cracking effect of the two catalysts on 16 different species of PAHs.


2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Muhammad Nadeem Amin ◽  
Yi Li ◽  
Xingmei Lu

Lighter tars are largely useful in chemical industries but their quantity is quite little. Catalytic cracking is applied to improve the yield of light tars during pyrolysis. Consequently, in situ upgrading technique through a MoS2 catalyst has been explored in this research work. MoS2 catalyst is useful for the conversion of high energy cost into low energy cost. The variations in coal pyrolysis tar without and with catalyst were determined. Meanwhile, the obtained tar was analyzed using simulated distillation gas chromatograph and Elemental Analyzer. Consequently, the catalyst reduced the pitch contents and increased the fraction of light tar from 50 to 60 wt.% in coal pyrolysis tar. MoS2 catalyst increased the liquid yield from 18 to 33 (wt.%, db) and decreased gas yield from 27 to 12 (wt.%, db) compared to coal without catalyst. Moreover, it increased H content and hydrogen-to-carbon ratio by 7.9 and 3.3%, respectively, and reduced the contents of nitrogen, sulphur, and oxygen elements by 8.1%, 15.2%, and 23.9%, respectively, in their produced tars compared to coal without catalyst.


Fuel ◽  
1986 ◽  
Vol 65 (9) ◽  
pp. 1315-1316 ◽  
Author(s):  
M SEEHRA ◽  
B GHOSH ◽  
S MULLINS
Keyword(s):  

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