Metal‐Organic Frameworks of Cu 3 (BTC) 2 Catalyzed Cascade C‐H Activation/C‐S Coupling/C‐O Cyclization Reaction Strategy: One‐Pot Efficient Synthesis of Phenoxathiines

2019 ◽  
Vol 4 (37) ◽  
pp. 11177-11180 ◽  
Author(s):  
Na Liu ◽  
Fei Chao ◽  
Jiaying Yan ◽  
Nian‐Yu Huang ◽  
Zhi‐Lin Ren ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Cyclization Reaction ◽  
Efficient Synthesis ◽  
One Pot ◽  
Metal Organic

scholarly journals A Facile One-Pot Approach to the Synthesis of Gd-Eu Based Metal-Organic Frameworks and Applications to Sensing of Fe3+ and Cr2O72− Ions

Sensors ◽  
2021 ◽  
Vol 21 (5) ◽  
pp. 1679
Author(s):  
Roberta Puglisi ◽  
Anna L. Pellegrino ◽  
Roberto Fiorenza ◽  
Salvatore Scirè ◽  
Graziella Malandrino
Keyword(s):  
Surface Area ◽  
Metal Organic Frameworks ◽  
3D Structure ◽  
Inorganic Ions ◽  
Total Surface Area ◽  
One Pot ◽  
Green Approach ◽  
Metal Organic ◽  
Ft Ir ◽  
Xrd Patterns

Gadolinium metal-organic frameworks (Gd-MOFs) and Eu-doped Gd-MOFs have been synthesized through a one-pot green approach using commercially available reagents. The 1,4-benzenedicarboxylic acid (H2-BDC) and 2,6-naphthalenedicarboxylic acid (H2-NDC) were chosen as ditopic organic linkers to build the 3D structure of the network. The Gd-MOFs were characterized using powder X-ray diffraction (XRD), FT-IR spectroscopy, field emission scanning electron microscopy (FE-SEM) and N2 adsorption–desorption analysis. The Gd-MOF structures were attributed comparing the XRD patterns, supported by the FT-IR spectra, with data reported in the literature for Ln-MOFs of similar lanthanide ionic radius. FE-SEM characterization points to the effect of the duration of the synthesis to a more crystalline and organized structure, with grain dimensions increasing upon increasing reaction time. The total surface area of the MOFs has been determined from the application of the Brunauer–Emmett–Teller method. The study allowed us to correlate the processing conditions and ditopic linker dimension to the network surface area. Both Gd-MOF and Eu-doped Gd-MOF have been tested for sensing of the inorganic ions such as Fe3+ and Cr2O72−.

Petal-shaped MOF assembled with gold nanocage and urate oxidase used as artificial enzyme nanohybrid for tandem catalysis and dual-channel biosensing

Nanoscale ◽  
2021 ◽  
Author(s):  
Zejun Sun ◽  
Yujiao Sun ◽  
Meng Yang ◽  
Hui Jin ◽  
Rijun Gui
Keyword(s):  
Metal Organic Frameworks ◽  
Urate Oxidase ◽  
Tandem Catalysis ◽  
Artificial Enzyme ◽  
One Pot ◽  
Mild Conditions ◽  
Dual Channel ◽  
Metal Organic

A facile one-pot precipitation was employed to prepare a petal-shaped hybrid in mild conditions. The hybrid is composed of urate oxidase (UOx) encapsulated into zeolite-like metal-organic frameworks (MOF) with doping...

One-pot synthesis of binary metal organic frameworks (HKUST-1 and UiO-66) for enhanced adsorptive removal of water contaminants

2017 ◽  
Vol 490 ◽  
pp. 685-694 ◽  
Author(s):  
Muhammad Rizwan Azhar ◽  
Hussein Rasool Abid ◽  
Hongqi Sun ◽  
Vijay Periasamy ◽  
Moses O. Tadé ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
One Pot ◽  
Water Contaminants ◽  
Adsorptive Removal ◽  
Binary Metal ◽  
One Pot Synthesis ◽  
Metal Organic

One-pot synthesis of hierarchical-pore metal–organic frameworks for drug delivery and fluorescent imaging

CrystEngComm ◽  
2018 ◽  
Vol 20 (8) ◽  
pp. 1087-1093 ◽  
Author(s):  
Xuechuan Gao ◽  
Yuewu Wang ◽  
Guanfeng Ji ◽  
Ruixue Cui ◽  
Zhiliang Liu
Keyword(s):  
Drug Delivery ◽  
Metal Organic Frameworks ◽  
Fluorescent Imaging ◽  
One Pot ◽  
One Pot Synthesis ◽  
Drug Molecules ◽  
Metal Organic ◽  
Hierarchical Pore

A one-pot process has been developed for the synthesis of hierarchical-pore metal–organic frameworks, aimed at loading large and small drug molecules simultaneously.

One-pot synthesis of bimetallic metal–organic frameworks (MOFs) as acid–base bifunctional catalysts for tandem reaction

2020 ◽  
Vol 10 (2) ◽  
pp. 315-322 ◽  
Author(s):  
Yanjing Hu ◽  
Jian Zhang ◽  
Hang Huo ◽  
Zhe Wang ◽  
Xianzhu Xu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Bifunctional Catalysts ◽  
Pore System ◽  
Acid Base ◽  
One Pot ◽  
System P ◽  
Synergistic Mechanism ◽  
Metal Organic ◽  
Hierarchical Pore System ◽  
Hierarchical Pore

Bimetallic MIL-101(Al/Fe)–NH2 exhibits enhanced acid–base bifunctional catalytic activity due to its synergistic mechanism and hierarchical pore system.

scholarly journals Second-order programming the synthesis of metal–organic frameworks

2020 ◽  
Vol 56 (82) ◽  
pp. 12355-12358
Author(s):  
Mitchell G. Fishburn ◽  
Dayne R. Skelton ◽  
Shane G. Telfer ◽  
Pawel Wagner ◽  
Christopher Richardson
Keyword(s):  
Metal Organic Frameworks ◽  
Second Order ◽  
One Pot ◽  
Metal Organic

The first example of ‘one-pot’ coordinate-covalent synthetic programming for metal–organic frameworks is reported.

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