Aerobic Oxidation of Thiols and In Situ Generated Thiols to Symmetrical Disulfides (Disulfanes) Catalyzed by Na 2 S 4 O 6

2019 ◽  
Vol 4 (42) ◽  
pp. 12227-12231 ◽  
Author(s):  
Mohammad Abbasi ◽  
Najmeh Nowrouzi ◽  
Saadat Mousavi
Keyword(s):  
Aerobic Oxidation ◽  
Symmetrical Disulfides

On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

2014 ◽  
Vol 3 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Hannes Alex ◽  
Norbert Steinfeldt ◽  
Klaus Jähnisch ◽  
Matthias Bauer ◽  
Sandra Hübner
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
X Ray ◽  
X Ray Scattering ◽  
Oxidation Of Benzyl Alcohol ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

scholarly journals First in situ vesicular self-assembly of ‘binols’ generated by a two-component aerobic oxidation reaction

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 29155-29163 ◽  
Author(s):  
Braja G. Bag ◽  
Subrata Ghorai ◽  
Saikat K. Panja ◽  
Shaishab K. Dinda ◽  
Koushik Paul
Keyword(s):  
Self Assembly ◽  
Oxidation Reaction ◽  
Aerobic Oxidation ◽  
Alkyl Chains ◽  
Two Component ◽  
Donor Acceptor ◽  
Self Assembled ◽  
Naphthol Derivatives

Binol derivatives, obtained by aerobic coupling of two 2-naphthol derivatives having H-bond donor–acceptor groups and appended alkyl chains, spontaneously self-assembled in situ yielding vesicular self-assemblies and gels.

In situ assembly of ultrafine Mn3O4 nanoparticles into MIL-101 for selective aerobic oxidation

2017 ◽  
Vol 7 (18) ◽  
pp. 4136-4144 ◽  
Author(s):  
Yu Fu ◽  
Yanglong Guo ◽  
Yun Guo ◽  
Yunsong Wang ◽  
Li Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Oxides ◽  
Aerobic Oxidation ◽  
High Catalytic Activity ◽  
Selective Aerobic Oxidation ◽  
Mn3o4 Nanoparticles

Nanosize metal oxides generally possess high catalytic activity, but they tend to agglomerate into larger particles during a reaction.

ChemInform Abstract: In situ Formation of NOx and Br Anion for Aerobic Oxidation of Benzylic Alcohols Without Transition Metal.

ChemInform ◽  
2010 ◽  
Vol 41 (24) ◽  
pp. no-no
Author(s):  
Guanyu Yang ◽  
Wei Wang ◽  
Weimin Zhu ◽  
Cunbin An ◽  
Xinqin Gao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Aerobic Oxidation ◽  
Benzylic Alcohols ◽  
In Situ Formation

In situ Formation of NOx and Br Anion for Aerobic Oxidation of Benzylic Alcohols without Transition Metal

Synlett ◽  
2010 ◽  
Vol 2010 (03) ◽  
pp. 437-440 ◽  
Author(s):  
Guanyu Yang ◽  
Maoping Song ◽  
Wei Wang ◽  
Weimin Zhu ◽  
Cunbin An ◽  
...  
Keyword(s):  
Transition Metal ◽  
Aerobic Oxidation ◽  
Benzylic Alcohols ◽  
In Situ Formation
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