Schiff Base/CuI as a Novel Efficient Catalyst System for Cu–Catalyzed Heck Reaction in Water

2019 ◽  
Vol 4 (33) ◽  
pp. 9673-9676
Author(s):  
Yufang Wang ◽  
Mingjie Zhang
Keyword(s):  
Schiff Base ◽  
Heck Reaction ◽  
Catalyst System ◽  
Efficient Catalyst ◽  
Reaction In Water

A High-Throughput Approach to Discovery: Heck-Type Reactivity with Aldehydes

Synlett ◽  
2018 ◽  
Vol 29 (16) ◽  
pp. 2081-2086 ◽  
Author(s):  
Stephen Newman ◽  
Jaya Vandavasi
Keyword(s):  
High Throughput ◽  
Heck Reaction ◽  
Catalyst System ◽  
Heck Reactions ◽  
Efficient Catalyst ◽  
High Throughput Experimentation ◽  
Olefin Coupling ◽  
Coupling Partner ◽  
Intermolecular Coupling

The classical Heck reaction is among the most powerful methods available for the construction of C–C bonds. Modification of this transformation to utilize diverse organohalide coupling partners has resulted in new reactions such as the silyl-Heck, aza-Heck, and boryl-Heck reactions. In contrast, modification of the olefin coupling partner is rare. For instance, use of the π-bond of an aldehyde instead of an alkene would provide ketones via a carbonyl-Heck process. This seemingly minor manipulation of the Heck reaction has proven surprisingly difficult to realize in practice. Through the use of high-throughput ­experimentation techniques, an efficient catalyst system for this transformation was identified, enabling the intermolecular coupling of ­organotriflates and aldehydes to synthesize diverse ketones.

Mn(OAc)2/Schiff base as a new efficient catalyst system for the Henry reaction of nitroalkanes with aldehydes

2012 ◽  
Vol 23 (6) ◽  
pp. 690-694 ◽  
Author(s):  
Guang Peng Zhou ◽  
Yong Hai Hui ◽  
Ning Ning Wan ◽  
Qiu Ju Liu ◽  
Zheng Feng Xie ◽  
...  
Keyword(s):  
Schiff Base ◽  
Catalyst System ◽  
Henry Reaction ◽  
Efficient Catalyst

ChemInform Abstract: Mn(OAc)2/Schiff Base as a New Efficient Catalyst System for the Henry Reaction of Nitroalkanes with Aldehydes.

ChemInform ◽  
2013 ◽  
Vol 44 (3) ◽  
pp. no-no
Author(s):  
Guang Peng Zhou ◽  
yong Hai Hui ◽  
Ning Ning Wan ◽  
Qiu Ju Liu ◽  
Zheng Feng Xie ◽  
...  
Keyword(s):  
Schiff Base ◽  
Catalyst System ◽  
Henry Reaction ◽  
Efficient Catalyst

Mont-K10 Supported Fe(II) Schiff-Base Complex as an Efficient Catalyst for Hydrogenation of Ketones

2019 ◽  
Vol 149 (8) ◽  
pp. 2142-2157 ◽  
Author(s):  
Samim Sultana ◽  
Geetika Borah ◽  
Pradip. K. Gogoi
Keyword(s):  
Schiff Base ◽  
Schiff Base Complex ◽  
Efficient Catalyst ◽  
Base Complex
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