Solution Route to Single-Crystalline Ethylammonium Lead Halide Microstructures

2019 ◽  
Vol 4 (7) ◽  
pp. 2174-2180
Author(s):  
Dewei Ma ◽  
Ning Dai ◽  
Yuguo Lan
CrystEngComm ◽  
2011 ◽  
Vol 13 (20) ◽  
pp. 6045 ◽  
Author(s):  
Guo Gao ◽  
Wenjun Gao ◽  
Xinqiu Guo ◽  
Hong Wang ◽  
Haixia Wu ◽  
...  

Carbon ◽  
2007 ◽  
Vol 45 (6) ◽  
pp. 1160-1166 ◽  
Author(s):  
Guo-Xing Zhu ◽  
Xian-Wen Wei ◽  
Chuan-Jun Xia ◽  
Yin Ye

RSC Advances ◽  
2018 ◽  
Vol 8 (26) ◽  
pp. 14527-14531 ◽  
Author(s):  
Wenhao Zhai ◽  
Chaoyang Ge ◽  
Xin Fang ◽  
Kun Zhang ◽  
Cheng Tian ◽  
...  

We report an acetone vapour-assisted method to grow single-crystalline 2D perovskite microplates and find their temperature-enhanced photoluminescence.


2018 ◽  
Vol 115 (47) ◽  
pp. 11929-11934 ◽  
Author(s):  
Minliang Lai ◽  
Amael Obliger ◽  
Dylan Lu ◽  
Christopher S. Kley ◽  
Connor G. Bischak ◽  
...  

Facile ionic transport in lead halide perovskites plays a critical role in device performance. Understanding the microscopic origins of high ionic conductivities has been complicated by indirect measurements and sample microstructural heterogeneities. Here, we report the direct visualization of halide anion interdiffusion in CsPbCl3–CsPbBr3 single crystalline perovskite nanowire heterojunctions using wide-field and confocal photoluminescence measurements. The combination of nanoscale imaging techniques with these single crystalline materials allows us to measure intrinsic anionic lattice diffusivities, free from complications of microscale inhomogeneity. Halide diffusivities were found to be between 10−13 and ∼10−12 cm2/second at about 100 °C, which are several orders of magnitudes lower than those reported in polycrystalline thin films. Spatially resolved photoluminescence lifetimes and surface potential measurements provide evidence of the central role of halide vacancies in facilitating ionic diffusion. Vacancy formation free energies computed from molecular simulation are small due to the easily deformable perovskite lattice, accounting for the high equilibrium vacancy concentration. Furthermore, molecular simulations suggest that ionic motion is facilitated by low-frequency lattice modes, resulting in low activation barriers for vacancy-mediated transport. This work elucidates the intrinsic solid-state ion diffusion mechanisms in this class of semisoft materials and offers guidelines for engineering materials with long-term stability in functional devices.


2006 ◽  
Vol 110 (37) ◽  
pp. 18225-18230 ◽  
Author(s):  
Zhengtao Deng ◽  
Fangqiong Tang ◽  
Dong Chen ◽  
Xianwei Meng ◽  
Li Cao ◽  
...  

2021 ◽  
Vol 57 (15) ◽  
pp. 1939-1942
Author(s):  
Na Lu ◽  
Di Wang ◽  
Meina Han ◽  
Bojin Zhao ◽  
Guozheng Wu ◽  
...  

Nano-thick 2D FAPbBr3 single-crystalline sheets were grown via a liquid-phase epitaxy method, and their optics and optoelectronic performances were revealed.


2005 ◽  
pp. 507 ◽  
Author(s):  
Shuai Wang ◽  
Songhai Xie ◽  
Hexing Li ◽  
Shirun Yan ◽  
Kangnian Fan ◽  
...  

2019 ◽  
Vol 7 (27) ◽  
pp. 8357-8363 ◽  
Author(s):  
Juan Gao ◽  
Qiangbing Liang ◽  
Guohui Li ◽  
Ting Ji ◽  
Yucheng Liu ◽  
...  

A single crystalline perovskite thin wafer is prepared using the seed-induced crystallization method and its photodetection on/off current ratio is 4.3 thousand.


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