Stability of the Monoelectronic Reduction Product from 1,2,5‐Thiadiazole S,S‐Dioxides. Electrochemical, Chemical, and Photoinduced Doping

2018 ◽  
Vol 3 (30) ◽  
pp. 8729-8739 ◽  
Author(s):  
José A. Caram ◽  
Julyleth P. Jiménez Macías ◽  
Nelson Rodríguez Arroyo ◽  
Jaime F. Martínez Suárez ◽  
Ana M. Gennaro ◽  
...  
Keyword(s):  
2011 ◽  
Vol 6 (11) ◽  
pp. 1934578X1100601
Author(s):  
Karsten Krohn ◽  
Stephan Cludius-Brandt ◽  
Barbara Schulz ◽  
Mambatta Sreelekha ◽  
Pottachola Mohamed Shafi

Several biologically active alkaloids (1-4, 6), including a new quinazoline-6-carboxylic acid (1), were isolated from the medicinal plant Zanthoxylum rhetsa, an evergreen tree, native to subtropical areas. Whereas the pharmacological properties of the plant extract and single constituents have been widely tested, we now show that all of the metabolites have antialgal activities, all but 6 are antibacterial, and 6 and the reduction product 5 (derived from 4) are also antifungal.


Author(s):  
Uilame Umbelino Gomes ◽  
Angelus Guiseppe Pereira da Silva ◽  
Jose Nilson Franca de Holanda ◽  
Daltro Garcia Pinatti

1980 ◽  
Vol 58 (19) ◽  
pp. 2069-2072 ◽  
Author(s):  
A. Stoessl ◽  
J. B. Stothers

The complement of sesquiterpenoidal stress compounds produced in the interaction of potato with the pathogenic fungus, Alternariasolani, includes representatives of a new stereochemical series, 2-epilubimin (1) and its reduction product, 15-dihydro-2-epilubimin (3). Their structures were deduced from 13C and 1H magnetic resonance data.


1966 ◽  
Vol 44 (11) ◽  
pp. 1247-1258 ◽  
Author(s):  
Raj Nandan Prasad ◽  
Karin Tietje

The formation of 3-oxo-3,4-dihydro-2H-1,4-benzothiazine (IIIa) by cyclization of alkyl 2-haloacetamidophenyl sulfides (I) was investigated; it is proposed that the reaction proceeds via a six-membered sulfonium halide. The preparation of 4-alkyl derivatives of IIIa and of 4-alkyl and 4-acyl derivatives of its reduction product 3,4-dihydro-2H-1,4-benzothiazine (Va) is described. Acylation of Va was shown to proceed without opening of the thiazine ring. Preparation of the O-benzoyl, N-benzoyl, and O,N-dibenzoyl derivatives of 2-(β-hydroxyethyl-mercapto)aniline (VIII) has permitted clarification of the confusion in the literature with respect to the derivatives of Va and VIII. Compound XVIII, the 1,1-dioxide of IIIa, undergoes C-alkylation at the 2-position when treated with alkyl halides, rather than O-alkylation as previously suggested.


1956 ◽  
Vol 32 (1) ◽  
pp. 53-58 ◽  
Author(s):  
Hiroshi IKEDA ◽  
Kenji SHIROYANAGI ◽  
Hatsuko IKEDA ◽  
Kei-ichi TSUJI ◽  
Mitsuhiko KATAYAMA ◽  
...  
Keyword(s):  

1963 ◽  
Vol 41 (6) ◽  
pp. 1485-1489 ◽  
Author(s):  
Y. Tsuda ◽  
Léo Marion

An alkaloid isolated from Aconitum spicatum Stapf has been found to be identical not only with the originally described pseudaconitine but also with 'α-pseudaconitine'. The product of the partial hydrolysis of the base, i.e., veratroylpseudaconine, is dextrorotatory, and not laevorotatory as recorded in the old literature. On heating, pseudaconitine undergoes pyrolysis, loses the elements of acetic acid, and gives rise to pyropseudaconitine. This substance, on treatment with lithium aluminum hydride, is converted to demethoxyisopyropseudaconine which is identical with the Wolff–Kishner reduction product of pyraconine. This correlation establishes that pseudaconitine and aconitine possess the same absolute configuration, which, in the light of previous knowledge, is extended also to indaconitine, delphinine, mesaconitine, and jesaconitine.


2008 ◽  
Vol 99 (6) ◽  
pp. 446-450 ◽  
Author(s):  
Stephanie S. Harvard ◽  
Warren D. Hill ◽  
Jane A. Buxton

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