A Complementary XRD and Theoretical Study of Water Induced Solid State Ionic Separation of Br− and Pyrazolium: A Case for Paradoxical Cation-Water Cluster

2017 ◽  
Vol 2 (19) ◽  
pp. 5288-5291
Author(s):  
Krishna Sundar Das ◽  
Arijit Goswami ◽  
Pabitra Narayan Samanta ◽  
Kalyan Kumar Das ◽  
Raju Mondal
Keyword(s):  
Solid State ◽  
Solid State Ionic ◽  
Water Cluster ◽  
Theoretical Study ◽  
State Ionic

Preparation and electrochemical properties of Li0.33Sr La0.56–2/3TiO3-based solid-state ionic supercapacitor

2019 ◽  
Vol 45 (2) ◽  
pp. 2584-2590 ◽  
Author(s):  
Dong-liang Lu ◽  
Jiu-ming Ma ◽  
Jia-lin Wu ◽  
Ying-bang Yao ◽  
Tao Tao ◽  
...  
Keyword(s):  
Solid State ◽  
Electrochemical Properties ◽  
Solid State Ionic ◽  
State Ionic

Flexible and non-volatile redox active quasi-solid state ionic liquid based electrolytes for thermal energy harvesting

2018 ◽  
Vol 2 (8) ◽  
pp. 1806-1812 ◽  
Author(s):  
Abuzar Taheri ◽  
Douglas R. MacFarlane ◽  
Cristina Pozo-Gonzalo ◽  
Jennifer M. Pringle
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Energy Harvesting ◽  
Thermal Energy ◽  
Solid State Ionic ◽  
Waste Heat ◽  
Low Grade ◽  
Redox Active ◽  
Thermal Energy Harvesting ◽  
State Ionic

Towards the development of stable thermocells for harvesting low-grade waste heat, non-volatile and flexible electrolyte films are reported.

Conversion of covalent to ionic character of V2O5–CeO2–PbO–B2O3 glasses for solid state ionic devices

2012 ◽  
Vol 407 (21) ◽  
pp. 4269-4273 ◽  
Author(s):  
Gurinder Pal Singh ◽  
Parvinder Kaur ◽  
Simranpreet Kaur ◽  
D.P. Singh
Keyword(s):  
Solid State ◽  
Solid State Ionic ◽  
Ionic Character ◽  
Ionic Devices ◽  
State Ionic

Photochemistry of 9-methylbicyclo[3.3.1]nonyl aryl ketones — A novel 1,5-disproportionation of 1,4-hydroxy biradicals and asymmetric induction using the solid-state ionic chiral auxiliary method

2005 ◽  
Vol 83 (9) ◽  
pp. 1460-1472 ◽  
Author(s):  
Shuang Chen ◽  
Brian O Patrick ◽  
John R Scheffer
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Solid State Ionic ◽  
Chiral Auxiliary ◽  
Asymmetric Induction ◽  
X Ray Crystallography ◽  
Aryl Ketones ◽  
Hydroxy Biradicals ◽  
Phenyl Ketones ◽  
State Ionic

A novel 1,5-disproportionation reaction has been discovered for 1,4-hydroxy biradicals derived from the photolysis of 9-methylbicyclo[3.3.1]nonyl phenyl ketones (1), which undergo mainly Yang cyclization both in solution and the solid state. By applying the solid-state ionic chiral auxiliary method of asymmetric synthesis to the Yang cyclization, enantiomeric excesses as high as 95% were achieved at high reaction conversions. The origin of the reaction selectivity is discussed with the help of X-ray crystallography. In addition, the solid-state photoreaction of ketone 1b was found to occur in a single crystal-to-single crystal fashion.Key words: photochemistry, 1,4-hydroxy biradical, disproportionation, asymmetric induction, ionic chiral auxiliary, single crystal-to-single crystal reaction.

Sign in / Sign up

Export Citation Format

Share Document