Interaction Behavior between Active Hydrogen Bond Donor-Acceptors as a Binding Decoration for Anion Recognition: Experimental Observation and Theoretical Validation

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A [2]rotaxane anion host that switches selectivity from dihydrogen phosphate to the halides upon substituting a hydrogen bond donor group for a halogen bond donor group within the axle component is described.


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The coupling of CO2 and epoxide is promising way to reduce atmospheric carbon by converting it into value-added cyclic carbonate. Pursuing efficient catalysts is highly attractive for the title reaction....


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