‘Reverse Micellar Aggregates’ in Phase Transfer Catalyzed Nucleophilic Displacement Reactions

2016 ◽  
Vol 1 (10) ◽  
pp. 2479-2484 ◽  
Author(s):  
Annadka Shrinidhi
Keyword(s):  
Phase Transfer ◽  
Micellar Aggregates ◽  
Nucleophilic Displacement ◽  
Displacement Reactions ◽  
Reverse Micellar

The gas phase reactivity of the dimethylchloronium ion with alkylbenzenes

1981 ◽  
Vol 59 (15) ◽  
pp. 2412-2416 ◽  
Author(s):  
John A. Stone ◽  
Margaret S. Lin ◽  
Jeffrey Varah
Keyword(s):  
High Pressure ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Aromatic Hydrocarbons ◽  
Relative Rate ◽  
Ion Source ◽  
Nucleophilic Displacement ◽  
Rate Of Reaction ◽  
Displacement Reactions ◽  
Bonded Complexes

The reactivity of the dimethylchloronium ion with a series of aromatic hydrocarbons has been studied in a high pressure mass spectrometer ion source using the technique of reactant ion monitoring. Benzene is unreactive but all others, from toluene to mesitylene, react by CH3+ transfer to yield σ-bonded complexes. The relative rate of reaction increases with increasing exothermicity in line with current theories of nucleophilic displacement reactions.

Reverse Micellar Aggregates:  Effect on Ketone Reduction. 2. Surfactant Role

2004 ◽  
Vol 69 (24) ◽  
pp. 8231-8238 ◽  
Author(s):  
N. Mariano Correa ◽  
Daniel H. Zorzan ◽  
Loredana D'Anteo ◽  
Ermanno Lasta ◽  
Marco Chiarini ◽  
...  
Keyword(s):  
Ketone Reduction ◽  
Micellar Aggregates ◽  
Reverse Micellar
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