Modeling electrochemical surface responses for PANI bronze corrosion protection

2016 ◽  
Vol 48 (13) ◽  
pp. 1402-1409
Author(s):  
Safa Aouadi ◽  
Nébil Souissi
Keyword(s):  
Corrosion Protection ◽  
Bronze Corrosion

scholarly journals Inclusion of 5-Mercapto-1-Phenyl-Tetrazole into β-Cyclodextrin for Entrapment in Silane Coatings: An Improvement in Bronze Corrosion Protection

Coatings ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 508 ◽  
Author(s):  
Cecilia Monticelli ◽  
Giancarlo Fantin ◽  
Graziano Di Carmine ◽  
Federica Zanotto ◽  
Andrea Balbo
Keyword(s):  
Corrosion Protection ◽  
Polarization Resistance ◽  
Corrosion Inhibitors ◽  
Organic Molecules ◽  
Corrosion Initiation ◽  
Silane Coating ◽  
Esi Mass Spectrometry ◽  
The Stability ◽  
Synthetic Acid ◽  
Bronze Corrosion

The corrosion protection of coatings can be reinforced by the addition of entrapped corrosion inhibitors. β-cyclodextrin (β-CD) can form inclusion complexes with small inhibiting organic molecules that, when entrapped in coatings, allow the inhibitor release and adsorption at corrosion initiation sites. In this paper, several Nuclear Magnetic Resonance (NMR)-based experiments (e.g., Complexation-Induced Shifts (CIS), NMR titration, Diffusion-Ordered Spectroscopy (DOSY)) were performed to study the stability and geometry of a complex formed by β-cyclodextrin with 5-mercapto-1-phenyl-tetrazole (MPT). The complex was also detected by Electrospray Ionization (ESI) mass spectrometry and characterized by Fourier Transform Infrared (FTIR) spectra. Its influence on the protectiveness of a silane coating against bronze corrosion was evaluated in plain (AR) and concentrated (ARX10) synthetic acid rain, under different exposure conditions. In particular, the time evolution of the polarization resistance values during 20 days in ARX10 and the polarization curves recorded at the end of the immersions evidenced a higher protectiveness of the coating with the β-CD–MPT complex in comparison to that containing only MPT or only β-CD. The cyclic AR spray test carried out on coated bronze coupons with cross-cut scratches evidenced the absence of underfilm corrosion starting from the scratches only in the complex-containing coating.

scholarly journals Atmospheric corrosion of fire-gilded bronze: corrosion and corrosion protection during accelerated ageing tests

2015 ◽  
Vol 100 ◽  
pp. 435-447 ◽  
Author(s):  
C. Chiavari ◽  
E. Bernardi ◽  
A. Balbo ◽  
C. Monticelli ◽  
S. Raffo ◽  
...  
Keyword(s):  
Corrosion Protection ◽  
Atmospheric Corrosion ◽  
Accelerated Ageing ◽  
Bronze Corrosion

CVD mullite and mullite-alumina corrosion protection coatings for silicon based ceramics

2001 ◽  
Vol 11 (PR3) ◽  
pp. Pr3-861-Pr3-867 ◽  
Author(s):  
S. M. Zemskova ◽  
J. A. Haynes ◽  
K. M. Cooley
Keyword(s):  
Corrosion Protection ◽  
Silicon Based

EIS study of the corrosion behavior of an organic coating applied on Algerian oil tanker

2020 ◽  
Vol 117 (6) ◽  
pp. 610
Author(s):  
Nadia Hammouda ◽  
Kamel Belmokre
Keyword(s):  
Corrosion Protection ◽  
Electrochemical Impedance ◽  
Paint Film ◽  
Organic Coating ◽  
Diffusion Resistance ◽  
Double Layer Capacitance ◽  
Carbon Steel Surface ◽  
Chloride Environment ◽  
Oil Tanker ◽  
Epoxy Paint

Organic coatings are widely employed in the corrosion protection of most metal surfaces, particularly steel. They provide a barrier against corrosive species present in the environment, due to their high resistance to oxygen, water and ions transport. This study focuses on the evaluation of corrosion protection performance of epoxy paint on the carbon steel surface in chloride environment (3% NaCl) by Electrochemical Impedance Spectroscopy (EIS). The electrochemical behavior of painted surface was estimated by EIS parameters that contained paint film resistance, paint film capacitance and double layer capacitance. On the basis of calculation using EIS spectrums it was observed that pore resistance (Rpore) decreased with the appearance of doubled layer capacitance (Cdl) due to the electrolyte penetration through the film. This was further confirmed by the decrease of diffusion resistance (Rd) which was also the indicator of the deterioration of paint film protectiveness. Microscopic analyses have shown that oxidation dominates the corroded surfaces.

AK STEEL 409 ULTRA FORM

Alloy Digest ◽  
2007 ◽  
Vol 56 (4) ◽  
Keyword(s):  
Stainless Steel ◽  
High Temperature ◽  
Carbon Steel ◽  
Physical Properties ◽  
Tensile Properties ◽  
Corrosion Protection ◽  
Automotive Exhaust ◽  
Standard Type ◽  
Temperature Performance ◽  
Complex Shapes

Abstract AK Steel 409 Ultra Form was created for applications needing oxidation or corrosion protection beyond the capability of carbon steel and some coated steels. AK Steel 409 Ultra Form is more formable than standard Type 409 stainless steel and is particularly suitable for parts requiring more complex shapes and improved weldability. Examples of applications include automotive exhaust tubing and stampings. This datasheet provides information on physical properties, hardness, elasticity, and tensile properties as well as deformation. It also includes information on high temperature performance as well as forming and joining. Filing Code: SS-990. Producer or source: AK Steel, Butler Operations.

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