An automated laser fluorination technique for high-precision analysis of three oxygen isotopes in silicates

2019 ◽  
Vol 33 (7) ◽  
pp. 641-649 ◽  
Author(s):  
Nak Kyu Kim ◽  
Minoru Kusakabe ◽  
Changkun Park ◽  
Jong Ik Lee ◽  
Keisuke Nagao ◽  
...  
2000 ◽  
Vol 39 (28) ◽  
pp. 5179 ◽  
Author(s):  
Seiichi Okuda ◽  
Takashi Nomura ◽  
Kazuhide Kamiya ◽  
Hiroshi Miyashiro ◽  
Kazuo Yoshikawa ◽  
...  

2018 ◽  
Vol 493 ◽  
pp. 100-108 ◽  
Author(s):  
Yan Hu ◽  
Xin-Yang Chen ◽  
Ying-Kui Xu ◽  
Fang-Zhen Teng

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 91 ◽  
Author(s):  
Kandy Wang ◽  
Ian Graham ◽  
Laure Martin ◽  
Panagiotis Voudouris ◽  
Gaston Giuliani ◽  
...  

In this study, the oxygen isotope (δ18O) composition of pink to red gem-quality rubies from Paranesti, Greece was investigated using in-situ secondary ionization mass spectrometry (SIMS) and laser-fluorination techniques. Paranesti rubies have a narrow range of δ18O values between ~0 and +1‰ and represent one of only a few cases worldwide where δ18O signatures can be used to distinguish them from other localities. SIMS analyses from this study and previous work by the authors suggests that the rubies formed under metamorphic/metasomatic conditions involving deeply penetrating meteoric waters along major crustal structures associated with the Nestos Shear Zone. SIMS analyses also revealed slight variations in δ18O composition for two outcrops located just ~500 m apart: PAR-1 with a mean value of 1.0‰ ± 0.42‰ and PAR-5 with a mean value of 0.14‰ ± 0.24‰. This work adds to the growing use of in-situ methods to determine the origin of gem-quality corundum and re-confirms its usefulness in geographic “fingerprinting”.


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