Experimental and theoretical studies of tautomers of nucleic acid bases

1987 ◽  
Vol 32 (S21) ◽  
pp. 765-766 ◽  
Author(s):  
Willis B. Person ◽  
Krystyna Szczepaniak ◽  
Marian Szczesniak ◽  
Jozef S. Kwiatkowski ◽  
Luis Hernandez
Keyword(s):  
Nucleic Acid ◽  
Theoretical Studies ◽  
Nucleic Acid Bases ◽  
Experimental And Theoretical Studies

Electron Binding to Nucleic Acid Bases. Experimental and Theoretical Studies. A Review

2004 ◽  
Vol 69 (7) ◽  
pp. 1395-1428 ◽  
Author(s):  
Daniel Svozil ◽  
Pavel Jungwirth ◽  
Zdeněk Havlas
Keyword(s):  
Nucleic Acid ◽  
Electron Attachment ◽  
Theoretical Studies ◽  
Biological Functions ◽  
Nucleic Acid Bases ◽  
Molecular Electronic ◽  
Dna And Rna ◽  
Theoretical Approaches ◽  
Experimental And Theoretical Studies ◽  
Electron Binding

An in-depth knowledge of an excess electron binding mechanism to DNA and RNA nucleobases is important for our understanding of radiation damage influence on the biological functions of nucleic acids, as well as for the possible use of DNA molecules as wires in molecular electronic circuits. The of anions created by electron attachment to individual nucleic acid bases is discussed in detail. The principles of the experimental and theoretical approaches to the description of these anions are outlined, and the available results concerning valence- and dipole-bound anions of nucleic acid bases are reviewed. A review with 167 references.

The Stabilizing Effect of Pre-Equilibria: A Trifluoromethyl Complex as CF2 Reservoir in Catalytic Olefin Difluorocarbenation

2020 ◽  
Author(s):  
Thomas Louis-Goff ◽  
Huu Vinh Trinh ◽  
Eileen Chen ◽  
Arnold L. Rheingold ◽  
Christian Ehm ◽  
...  
Keyword(s):  
High Selectivity ◽  
Side Reactions ◽  
Theoretical Studies ◽  
Attractive Feature ◽  
Catalyst Recovery ◽  
Wide Range ◽  
Stabilizing Effect ◽  
Experimental And Theoretical Studies

A new, efficient, catalytic difluorocarbenation of olefins to give 1,1-difluorocyclopropanes is presented. The catalyst, an organobismuth complex, uses TMSCF<sub>3</sub> as a stoichiometric difluorocarbene source. We demonstrate both the viability and robustness of this reaction over a wide range of alkenes and alkynes, including electron-poor alkenes, to generate the corresponding 1,1-difluorocyclopropanes and 1,1-difluorocyclopropenes. Ease of catalyst recovery from the reaction mixture is another attractive feature of this method. In depth experimental and theoretical studies showed that the key difluorocarbene-generating step proceeds through a bismuth non-redox synchronous mechanism generating a highly reactive free CF<sub>2</sub> in an endergonic pre-equilibrium. It is the reversibility when generating the difluorocarbene that accounts for the high selectivity, while minimizing CF<sub>2</sub>-recombination side-reactions.

Strong coupling: resonant effects

2017 ◽  
Author(s):  
Alexey V. Kavokin ◽  
Jeremy J. Baumberg ◽  
Guillaume Malpuech ◽  
Fabrice P. Laussy
Keyword(s):  
Strong Coupling ◽  
Experimental Studies ◽  
Strong Coupling Regime ◽  
Theoretical Studies ◽  
Stimulated Scattering ◽  
Quantum Theories ◽  
Pump Probe ◽  
Exciton Polaritons ◽  
Linear Optical Properties ◽  
Experimental And Theoretical Studies

This chapter presents experimental studies performed on planar semiconductor microcavities in the strong-coupling regime. The first section reviews linear experiments performed in the 1990s that evidence the linear optical properties of cavity exciton-polaritons. The chapter is then focused on experimental and theoretical studies of resonantly excited microcavity emission. We mainly describe experimental configuations in which stimulated scattering was observed due to formation of a dynamical condensate of polaritons. Pump-probe and cw experiments are described in addition. Dressing of the polariton dispersion and bistability of the polariton system due to inter-condensate interactions are discussed. The semiclassical and the quantum theories of these effects are presented and their results analysed. The potential for realization of devices is also discussed.

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