Unsaturation in binuclear iron carbonyl complexes of the split (3 + 2) five‐electron donor hydrocarbon ligand bicyclo[3.2.1]octa‐2,6‐dien‐4‐yl: Role of agostic hydrogen atoms

2019 ◽  
Vol 119 (22) ◽  
Author(s):  
Di Wan ◽  
Huidong Li ◽  
Liming Shi ◽  
Xueke Wu ◽  
Qunchao Fan ◽  
...  
Keyword(s):  
Electron Donor ◽  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Hydrogen Atoms ◽  
Binuclear Iron

Coupling of trifluoromethyl isocyanide ligands in binuclear iron carbonyl complexes

2014 ◽  
Vol 166 ◽  
pp. 34-43 ◽  
Author(s):  
Guoliang Li ◽  
Lihua Liu ◽  
Jing Wang ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Isocyanide Ligands ◽  
Binuclear Iron

ChemInform Abstract: BINUCLEAR IRON CARBONYL COMPLEXES WITH NITROGEN-CONTAINING BRIDGES

1979 ◽  
Vol 10 (26) ◽  
Author(s):  
A. N. NESMEYANOV ◽  
M. I. RYBINSKAYA ◽  
L. V. RYBIN
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Binuclear Iron

Alkylindium(I) vs Carbon Monoxide Bridges in Binuclear Iron Carbonyl Complexes:  A Theoretical Study

2001 ◽  
Vol 20 (4) ◽  
pp. 786-789 ◽  
Author(s):  
André Barthel ◽  
Carlo Mealli ◽  
Werner Uhl ◽  
Joachim Reinhold
Keyword(s):  
Carbon Monoxide ◽  
Theoretical Study ◽  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Binuclear Iron

Alternative modes of bonding of C4F8 units in mononuclear and binuclear iron carbonyl complexes

2019 ◽  
Vol 43 (18) ◽  
pp. 6932-6942 ◽  
Author(s):  
Liping Huang ◽  
Jing Li ◽  
Guoliang Li ◽  
Yaoming Xie ◽  
R. Bruce King ◽  
...  
Keyword(s):  
Activation Energies ◽  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Binuclear Iron ◽  
Very High

The lowest energy C4F8Fe(CO)4 structure is not the experimentally known ferracyclopentane complex but instead isomeric (perfluorobutene)iron tetracarbonyls. However, activation energies for the fluorine shifts required to form the latter isomers are very high. The lowest energy (C4F8)2Fe2(CO)n (n = 7, 6) structures have bridging perfluorocarbene and terminal perfluoroolefin ligands.

ChemInform Abstract: THE SYNTHESIS OF BINUCLEAR IRON CARBONYL COMPLEXES WITH DIMETHYLAMINOALLYL LIGAND

1976 ◽  
Vol 7 (49) ◽  
pp. no-no
Author(s):  
A. N. NESMEYANOV ◽  
L. V. RYBIN ◽  
A. A. POGREBNYAK ◽  
M. I. RYBINSKAYA
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Binuclear Iron

Binuclear iron carbonyl complexes of thialene

RSC Advances ◽  
2016 ◽  
Vol 6 (86) ◽  
pp. 82661-82668 ◽  
Author(s):  
Rong Jin ◽  
Xiaohong Chen ◽  
Quan Du ◽  
Hao Feng ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Low Energy ◽  
Carbonyl Complexes ◽  
Metal Bonding ◽  
Binuclear Iron

The low energy (thialene)Fe2(CO)6 structure has an η4,η4-thialene ligand bonded to two Fe(CO)3 units. The low-energy (thialene)Fe2(CO)5 structure has an η5,η3 thialene ligand bonded to an Fe2(CO)5 unit. Sulfur is not involved in ligand-metal bonding.

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