scholarly journals Enzymatic “tricks”: Carboxylate shift and sulfur shift

2014 ◽  
Vol 114 (19) ◽  
pp. 1253-1256 ◽  
Author(s):  
Sérgio F. Sousa ◽  
Nuno M. F. S. A. Cerqueira ◽  
Natércia F. Brás ◽  
Pedro A. Fernandes ◽  
Maria J. Ramos
Keyword(s):  
Carboxylate Shift

scholarly journals Factors Affecting the Carboxylate Shift Upon Formation of Nonheme Diiron-O2 Adducts

2013 ◽  
Vol 52 (5) ◽  
pp. 2627-2636 ◽  
Author(s):  
Jonathan R. Frisch ◽  
Ryan McDonnell ◽  
Elena V. Rybak-Akimova ◽  
Lawrence Que
Keyword(s):  
Factors Affecting ◽  
Carboxylate Shift

The Effect of Solvent on Isomer Formation. Synthesis and Crystal Structures of CdII Complexes with 3-Nitrobenzoate and Thiourea

2002 ◽  
Vol 55 (9) ◽  
pp. 611 ◽  
Author(s):  
S.-L. Zheng ◽  
W. Li ◽  
G. Yang ◽  
X.-M. Chen ◽  
H.-G. Zhu ◽  
...  
Keyword(s):  
Solvent Effect ◽  
Crystal Structures ◽  
The Other ◽  
Orthorhombic Space Group ◽  
Triclinic Space Group ◽  
Crystal Forms ◽  
Space Group ◽  
Water Solutions ◽  
Effect Of Solvent ◽  
Carboxylate Shift

Two crystal forms of bis(3-nitrobenzoato)bis(thiourea)cadmium(II) were obtained by the reaction of Cd(NO3)2�4H2O, 3-nitrobenzoate (mNA) and thiourea (TU) from ethanol and water solutions, respectively. One is cube-shaped and crystallizes in the orthorhombic space group Pbca and consists of discrete mononuclear molecules of bis(3-nitrobenzoato-O,O�)bis(thiourea)cadmium(II) (1). The other form is needle shaped and crystallizes in the triclinic space group P1–.It is comprised of discrete molecules of bis(3-nitrobenzoato-O,O�)bis(thiourea)cadmium(II) (2) and (3-nitrobenzoato-O,O�)(3-nitrobenzoato-O)bis(thiourea)cadmium(II) (3). (1), (2) and (3) are isomers, in which (1) may be regarded as a structural intermediate between (2) and (3) in the 'carboxylate shift' process. The formation of these isomers may be influenced by the solvent effect.

Alkali metal-responsive geometric and spectral changes in a cobalt(II) complex of a constrained dicarboxylate: a carboxylate shift-mediated metallochromoionophore

1995 ◽  
Vol 235 (1-2) ◽  
pp. 195-204 ◽  
Author(s):  
Stephen P. Watton ◽  
Mindy I. Davis ◽  
Laura E. Pence ◽  
Julius Rebek ◽  
Stephen J. Lippard
Keyword(s):  
Alkali Metal ◽  
Spectral Changes ◽  
Carboxylate Shift

Sequence of Metal-Organic Oligomer-Polymer Exchange Equilibria in Solution: Supramolecular Isomerism, Self-Assembly Dynamics and Carboxylate Shift of Di-n-butyltincis-1,4-Cyclohexanedicarboxylate

2008 ◽  
Vol 2008 (8) ◽  
pp. 1200-1204 ◽  
Author(s):  
Irán Fernando Hernández-Ahuactzi ◽  
Jorge Cruz-Huerta ◽  
Victor Barba ◽  
Herbert Höpfl ◽  
Luis S. Zamudio-Rivera ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Isomerism ◽  
Metal Organic ◽  
Carboxylate Shift

Visualising the carboxylate shift at a bioinspired diiron(ii) site in the solid state

2011 ◽  
Vol 47 (37) ◽  
pp. 10428 ◽  
Author(s):  
Boris Burger ◽  
Sebastian Dechert ◽  
Christian Große ◽  
Serhiy Demeshko ◽  
Franc Meyer
Keyword(s):  
Solid State ◽  
Carboxylate Shift

The Carboxylate Shift in Zinc Enzymes: A Computational Study

2007 ◽  
Vol 129 (5) ◽  
pp. 1378-1385 ◽  
Author(s):  
Sérgio F. Sousa ◽  
Pedro A. Fernandes ◽  
Maria João Ramos
Keyword(s):  
Computational Study ◽  
Zinc Enzymes ◽  
Carboxylate Shift
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