Theoretical study on the mechanisms of the nucleophilic substitution reactions of hydrosulfide ion and halomethanes

2010 ◽  
Vol 111 (14) ◽  
pp. 3643-3653 ◽  
Author(s):  
Jianyong He ◽  
Zhengwen Long ◽  
Jian Jing ◽  
Jin-Sheng Zhang
Keyword(s):  
Nucleophilic Substitution ◽  
Theoretical Study ◽  
Substitution Reactions ◽  
Nucleophilic Substitution Reactions

Nucleofugality hierarchy, in the aminolysis reaction of 4-cyanophenyl 4-nitrophenyl carbonate and thionocarbonate. Experimental and theoretical study

2021 ◽  
Author(s):  
Rodrigo Montecinos ◽  
M. Aliaga ◽  
Paulina Pavez ◽  
Patricio Cornejo ◽  
Jose G Santos
Keyword(s):  
Nucleophilic Substitution ◽  
Theoretical Study ◽  
Substitution Reactions ◽  
Nucleophilic Substitution Reactions ◽  
Group Effects

Nucleophilic substitution reactions of title compounds have been investigated with a series of secondary alicyclic amines in several solvents. The solvent, amine, and electrophilic group effects on kinetics, mechanism and...

The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4′,4′′-(MeOCH2CH2O)3-3,3′,3′′-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3]

2021 ◽  
Vol 50 (7) ◽  
pp. 2671-2688
Author(s):  
Marina Yu. Stogniy ◽  
Sergey A. Anufriev ◽  
Akim V. Shmal'ko ◽  
Sergey M. Antropov ◽  
Aleksei A. Anisimov ◽  
...  
Keyword(s):  
Nucleophilic Substitution ◽  
Substitution Reactions ◽  
Nucleophilic Substitution Reactions

An unusual reactivity of 9-iodo-nido-carborane [9-I-7,8-C2B9H11]− towards nucleophiles under strong basic conditions was revealed.

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