Enthalpy of Solvation Correlations For Gaseous Solutes Dissolved in Linear Alkanes (C5C16) Based on the Abraham Model

2008 ◽  
Vol 27 (2) ◽  
pp. 179-186 ◽  
Author(s):  
Christina Mintz ◽  
Katherine Burton ◽  
William E. Acree ◽  
Michael H. Abraham
Keyword(s):  
Enthalpy Of Solvation ◽  
Abraham Model ◽  
Linear Alkanes

Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Benzene and in Alkane Solvents Based on the Abraham Model

2007 ◽  
Vol 26 (8) ◽  
pp. 881-888 ◽  
Author(s):  
Christina Mintz ◽  
Michael Clark ◽  
Katherine Burton ◽  
William E. Acree ◽  
Michael H. Abraham
Keyword(s):  
Enthalpy Of Solvation ◽  
Abraham Model ◽  
Alkane Solvents

scholarly journals Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Water and in 1-Octanol Based on the Abraham Model

2006 ◽  
Vol 47 (1) ◽  
pp. 115-121 ◽  
Author(s):  
Christina Mintz ◽  
Michael Clark ◽  
William E. Acree, ◽  
Michael H. Abraham
Keyword(s):  
Enthalpy Of Solvation ◽  
Abraham Model

Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Toluene and Carbon Tetrachloride Based on the Abraham Model

2007 ◽  
Vol 36 (8) ◽  
pp. 947-966 ◽  
Author(s):  
Christina Mintz ◽  
Michael Clark ◽  
Katherine Burton ◽  
William E. Acree ◽  
Michael H. Abraham
Keyword(s):  
Carbon Tetrachloride ◽  
Enthalpy Of Solvation ◽  
Abraham Model

scholarly journals Enthalpy of solvation correlations for gaseous solutes dissolved in dimethyl sulfoxide and propylene carbonate based on the Abraham model

2007 ◽  
Vol 459 (1-2) ◽  
pp. 17-25 ◽  
Author(s):  
Christina Mintz ◽  
Katherine Burton ◽  
William E. Acree ◽  
Michael H. Abraham
Keyword(s):  
Dimethyl Sulfoxide ◽  
Propylene Carbonate ◽  
Enthalpy Of Solvation ◽  
Abraham Model

Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Alcohol Solvents based on the Abraham Model

2007 ◽  
Vol 27 (5) ◽  
pp. 627-635 ◽  
Author(s):  
Christina Mintz ◽  
Tara Ladlie ◽  
Katherine Burton ◽  
Michael Clark ◽  
William E. Acree ◽  
...  
Keyword(s):  
Enthalpy Of Solvation ◽  
Abraham Model ◽  
Alcohol Solvents

Abraham model enthalpy of solvation correlations for solutes dissolved in dimethyl carbonate and diethyl carbonate

2015 ◽  
Vol 53 (6) ◽  
pp. 732-747 ◽  
Author(s):  
Erin Hart ◽  
Damini Grover ◽  
Heidi Zettl ◽  
William E. Acree ◽  
Michael H. Abraham
Keyword(s):  
Dimethyl Carbonate ◽  
Diethyl Carbonate ◽  
Enthalpy Of Solvation ◽  
Abraham Model

scholarly journals Enthalpy of solvation correlations for gaseous solutes dissolved in chloroform and 1,2-dichloroethane based on the Abraham model

2007 ◽  
Vol 258 (2) ◽  
pp. 191-198 ◽  
Author(s):  
Christina Mintz ◽  
Katherine Burton ◽  
William E. Acree ◽  
Michael H. Abraham
Keyword(s):  
Enthalpy Of Solvation ◽  
Abraham Model

Intermolecular hydrogen transfer in unsaturated hydrocarbons induced by dimeric titanocene

1983 ◽  
Vol 48 (10) ◽  
pp. 2924-2936 ◽  
Author(s):  
Karel Mach ◽  
Lidmila Petrusová ◽  
Helena Antropiusová ◽  
Vladimír Hanuš ◽  
František Tureček ◽  
...  
Keyword(s):  
Hydrogen Transfer ◽  
Titanium Content ◽  
Esr Spectra ◽  
Stable Complex ◽  
Catalytic Complex ◽  
Substitution Reactions ◽  
Unsaturated Hydrocarbons ◽  
Linear Alkanes ◽  
Saturated And Aromatic Hydrocarbons ◽  
Intermolecular Hydrogen Transfer

μ-(η5 : η5-Fulvalene)-di-μ-hydrido-bis(η5-cyclopentadienyltitanium) and μ-(η5 : η5-fulvalene)-μ-chloro-μ-hydrido-bis(cyclopentadienyltitanium) form a thermally stable complex which catalyzes the intermolecular hydrogen transfer in unsaturated hydrocarbons, in addition to isomerizations and cyclizations. Cyclic hydrocarbons disproportionate under catalysis to saturated and aromatic hydrocarbons, while linear olefins yield predominantly linear alkanes and high molecular weight tar. The catalyst enables the hydrocarbon system to approach the thermodynamic equilibrium through a series of substitution reactions between alkyl- and allyltitanocene-like species and olefins and dienes. The catalytic complex was characterized by UV and ESR spectra. About one half of overall titanium content could be converted to mononuclear η3-allyltitanocene-like species, stable up to 400 °C. This exceptional thermal stability is ascribed to a firmly bound allyl containing ligand.

scholarly journals Oxidation of Organic Compounds with Peroxides Catalyzed by Polynuclear Metal Compounds

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 186
Author(s):  
Georgiy B. Shul’pin ◽  
Lidia S. Shul’pina
Keyword(s):  
Catalytic Reactions ◽  
Metal Salts ◽  
Polynuclear Complexes ◽  
Simple Metal ◽  
Metal Compounds ◽  
Mononuclear Complexes ◽  
Iron Copper ◽  
Linear Alkanes ◽  
Oxidation Of Organic Compounds ◽  
Nickel Manganese

The review describes articles that provide data on the synthesis and study of the properties of catalysts for the oxidation of alkanes, olefins, and alcohols. These catalysts are polynuclear complexes of iron, copper, osmium, nickel, manganese, cobalt, vanadium. Such complexes for example are: [Fe2(HPTB)(m-OH)(NO3)2](NO3)2·CH3OH·2H2O, where HPTB-¼N,N,N0,N0-tetrakis(2-benzimidazolylmethyl)-2-hydroxo-1,3-diaminopropane; complex [(PhSiO1,5)6]2[CuO]4[NaO0.5]4[dppmO2]2, where dppm-1,1-bis(diphenylphosphino)methane; (2,3-η-1,4-diphenylbut-2-en-1,4-dione)undecacarbonyl triangulotriosmium; phenylsilsesquioxane [(PhSiO1.5)10(CoO)5(NaOH)]; bi- and tri-nuclear oxidovanadium(V) complexes [{VO(OEt)(EtOH)}2(L2)] and [{VO(OMe)(H2O)}3(L3)]·2H2O (L2 = bis(2-hydroxybenzylidene)terephthalohydrazide and L3 = tris(2-hydroxybenzylidene)benzene-1,3,5-tricarbohydrazide); [Mn2L2O3][PF6]2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). For comparison, articles are introduced describing catalysts for the oxidation of alkanes and alcohols with peroxides, which are simple metal salts or mononuclear metal complexes. In many cases, polynuclear complexes exhibit higher activity compared to mononuclear complexes and exhibit increased regioselectivity, for example, in the oxidation of linear alkanes. The review contains a description of some of the mechanisms of catalytic reactions. Additionally presented are articles comparing the rates of oxidation of solvents and substrates under oxidizing conditions for various catalyst structures, which allows researchers to conclude about the nature of the oxidizing species. This review is focused on recent works, as well as review articles and own original studies of the authors.

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