Temperature behavior of the integral intensity of exciton absorption

1983 ◽  
Vol 115 (2) ◽  
pp. K87-K90 ◽  
Author(s):  
B. M. Nitsovich ◽  
G. M. Pestryakov
2004 ◽  
Author(s):  
V. M. Kramar ◽  
N. K. Kramar ◽  
Bohdan M. Nitsowich

2018 ◽  
Vol 56 (4) ◽  
pp. 527-532
Author(s):  
L. Kamaeva ◽  
◽  
A. Korepanov ◽  
V. Ladyanova ◽  
◽  
...  
Keyword(s):  

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3449
Author(s):  
Ireneusz Stefaniuk ◽  
Werner Obermayr ◽  
Volodymyr D. Popovych ◽  
Bogumił Cieniek ◽  
Iwona Rogalska

In this paper, we show a simple method of producing ferromagnetic materials with a Curie temperature above room temperature. The electron paramagnetic resonance (EPR) spectra of Cd1−xCrxTe (0.002 < x < 0.08) were measured with a dependence on temperature (82 K < T < 381 K). Obtained EPR lines were fitted to a Lorentz-shaped curve. The temperature dependencies of the parameters of the EPR lines, such as the peak-to-peak linewidth (Hpp), the intensity (A), as well as the resonance field (Hr), were studied. Ferromagnetism was noticed in samples at high temperatures (near room temperature). For a sample with a nominal concentration of chrome of x = 0.05, a very strong intrinsic magnetic field is observed. The value of the effective gyromagnetic factor for this sample is ge = 30 at T = 240 K. An increase of chrome concentration above x = 0.05 reduces the ferromagnetic properties considerably. Analysis of the temperature dependencies of the integral intensity of EPR spectra was carried out using the Curie–Weiss law and the paramagnetic Curie temperature was obtained.


Author(s):  
Mariola Kądziołka-Gaweł ◽  
Maria Czaja ◽  
Mateusz Dulski ◽  
Tomasz Krzykawski ◽  
Magdalena Szubka

AbstractMössbauer, Raman, X-ray diffraction and X-ray photoelectron spectroscopies were used to examine the effects of temperature on the structure of two aluminoceladonite samples. The process of oxidation of Fe2+ to Fe3+ ions started at about 350 °C for the sample richer in Al and at 300 °C for the sample somewhat lower Al-content. Mössbauer results show that this process may be associated with dehydroxylation or even initiate it. The first stage of dehydroxylation takes place at a temperature > 350 °C when the adjacent OH groups are replaced with a single residual oxygen atom. Up to ~500 °C, Fe ions do not migrate from cis-octahedra to trans-octahedra sites, but the coordination number of polyhedra changes from six to five. This temperature can be treated as the second stage of dehydroxylation. The temperature dependence on the integral intensity ratio between bands centered at ~590 and 705 cm−1 (I590/I705) clearly reflects the temperature at which six-coordinated polyhedra are transformed into five-coordinated polyhedra. X-ray photoelectron spectra obtained in the region of the Si2p, Al2p, Fe2p, K2p and O1s core levels, highlighted a route to identify the position of Si, Al, K and Fe cations in a structure of layered silicates with temperature. All the measurements show that the sample with a higher aluminum content and a lower iron content in octahedral sites starts to undergo a structural reorganization at a relatively higher temperature than the less aluminum-rich sample does. This suggests that iron may perform an important role in the initiation of the dehydroxylation of aluminoceladonites.


2021 ◽  
Author(s):  
Krati Joshi ◽  
Ashakiran Maibam ◽  
Sailaja Krishnamurty

Silicon carbide clusters are significant due to their predominant occurrence in meteoric star dust, particularly in carbon rich asymptotic giant branch stars. Of late, they have also been recognized as...


1995 ◽  
Vol 77 (5) ◽  
pp. 1934-1937 ◽  
Author(s):  
G. G. Fischer ◽  
P. Zaumseil ◽  
E. Bugiel ◽  
H. J. Osten

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1128
Author(s):  
Elisabetta Gariboldi ◽  
Stefano Spigarelli

The design of new alloys as well as the optimization of processes involving whichever form of high-temperature deformation cannot disregard the characterization and/or modelling of the high-temperature structural response of the material [...]


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