Long-range crystal-lattice distortion fields of epitaxial Ge-Sb-Te phase-change materials

2013 ◽  
Vol 251 (4) ◽  
pp. 769-773 ◽  
Author(s):  
Ferhat Katmis ◽  
Martin Schmidbauer ◽  
Sergiy M. Bokoch ◽  
Peter Rodenbach ◽  
Henning Riechert ◽  
...  
2014 ◽  
Vol 251 (4) ◽  
Author(s):  
Ferhat Katmis ◽  
Martin Schmidbauer ◽  
Sergiy M. Bokoch ◽  
Peter Rodenbach ◽  
Henning Riechert ◽  
...  

2005 ◽  
Vol 902 ◽  
Author(s):  
Alexei Grigoriev ◽  
Dal-Hyun Do ◽  
Dong Min Kim ◽  
Chang-Beom Eom ◽  
Bernhard Adams ◽  
...  

AbstractWhen an electric field is applied to a ferroelectric the crystal lattice spacing changes as a result of the converse piezoelectric effect. Although the piezoelectric effect and polarization switching have been investigated for decades there has been no direct nanosecond-scale visualization of these phenomena in solid crystalline ferroelectrics. Synchrotron x-rays allow the polarization switching and the crystal lattice distortion to be visualized in space and time on scales of hundreds of nanometers and hundreds of picoseconds using ultrafast x-ray microdiffraction. Here we report the polarization switching visualization and polarization domain wall velocities for Pb(Zr0.45Ti0.55)O3 thin film ferroelectric capacitors studied by time-resolved x-ray microdiffraction.


Author(s):  
C. Tabata ◽  
T. Inami ◽  
S. Michimura ◽  
M. Yokoyama ◽  
H. Hidaka ◽  
...  

2018 ◽  
Vol 54 (39) ◽  
pp. 4959-4962 ◽  
Author(s):  
Zhenhua Zhou ◽  
Waqas Qamar Zaman ◽  
Wei Sun ◽  
Li-mei Cao ◽  
Muhammad Tariq ◽  
...  

Enhancing the OER performance by cultivating Jahn–Teller distortion in IrO2 with Mn oxide being the substrate material.


2021 ◽  
Vol 63 (11) ◽  
pp. 1904-1908
Author(s):  
N. A. Koneva ◽  
L. I. Trishkina ◽  
T. V. Cherkasova ◽  
A. N. Solov’ev ◽  
N. V. Cherkasov

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3514
Author(s):  
Jiong Wang ◽  
Dongyu Cui ◽  
Yi Kong ◽  
Luming Shen

Unusual force constants originating from the local charge distribution in crystalline GeTe and Sb2Te3 are observed by using the first-principles calculations. The calculated stretching force constants of the second nearest-neighbor Sb-Te and Ge-Te bonds are 0.372 and −0.085 eV/Å2, respectively, which are much lower than 1.933 eV/Å2 of the first nearest-neighbor bonds although their lengths are only 0.17 Å and 0.33 Å longer as compared to the corresponding first nearest-neighbor bonds. Moreover, the bending force constants of the first and second nearest-neighbor Ge-Ge and Sb-Sb bonds exhibit large negative values. Our first-principles molecular dynamic simulations also reveal the possible amorphization of Sb2Te3 through local distortions of the bonds with weak and strong force constants, while the crystalline structure remains by the X-ray diffraction simulation. By identifying the low or negative force constants, these weak atomic interactions are found to be responsible for triggering the collapse of the long-range order. This finding can be utilized to guide the design of functional components and devices based on phase change materials with lower energy consumption.


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