In situSynthesized Energetic Salts Based on the C−N Fused Tricyclic 3,9-Diamine-6,7-Dihydro-Bis(triazolo)-Tetrazepine Cation: A Family of High-Performance Energetic Materials

2018 ◽  
Vol 43 (6) ◽  
pp. 595-601 ◽  
Author(s):  
Yuangang Xu ◽  
Zhongqin Zhu ◽  
Cheng Shen ◽  
Qiuhan Lin ◽  
Ming Lu
2015 ◽  
Vol 137 (33) ◽  
pp. 10532-10535 ◽  
Author(s):  
Jiaheng Zhang ◽  
Lauren A. Mitchell ◽  
Damon A. Parrish ◽  
Jean’ne M. Shreeve

2016 ◽  
Vol 45 (44) ◽  
pp. 17956-17965 ◽  
Author(s):  
Chuan Li ◽  
Man Zhang ◽  
Qishan Chen ◽  
Yingying Li ◽  
Huiqi Gao ◽  
...  

A new C–N linked heterocoupled energetic compound and its energetic salts have been prepared as heat-resistant energetic materials.


2015 ◽  
Vol 3 (28) ◽  
pp. 14768-14778 ◽  
Author(s):  
Long Liu ◽  
Yanqiang Zhang ◽  
Zhimin Li ◽  
Suojiang Zhang

4-R-5-Nitro-1,2,3-triazolate salts (R = –CH3, –NH2, –NO2, –N3, and –NHNO2) were systematically synthesized with nitrogen-rich cations. Among the energetic salts, dihydroxylaminium 4-nitramino-5-nitro-1,2,3-triazolate exhibits excellent energetic performance (38.8 GPa, 9464 m s−1).


2019 ◽  
Vol 43 (28) ◽  
pp. 11157-11163 ◽  
Author(s):  
Minxian Xu ◽  
Guangbin Cheng ◽  
Hualin Xiong ◽  
Bohan Wang ◽  
Xuehai Ju ◽  
...  

A new family of symmetric nitropyrazole and 1,2,4-triazole derivatives and its energetic salts were obtained. The positive effect of ternary hydrogen bonds improve the performances of target compounds.


2014 ◽  
Vol 2 (38) ◽  
pp. 15978-15986 ◽  
Author(s):  
Wei Liu ◽  
Sheng-hua Li ◽  
Yu-chuan Li ◽  
Yu-zhang Yang ◽  
Yi Yu ◽  
...  

A new family of high performance, nitrogen-rich energetic salts containing N,N′-azo linkage were synthesized through the protonation of 3,3′-diamino-4,4′-azobis-1,2,4-triazole.


2018 ◽  
Vol 24 (41) ◽  
pp. 10488-10497 ◽  
Author(s):  
Zhen Xu ◽  
Guangbin Cheng ◽  
Hongwei Yang ◽  
Jiaheng Zhang ◽  
Jean'ne M. Shreeve

2020 ◽  
Vol 842 ◽  
pp. 63-68
Author(s):  
Xiao Zhang ◽  
Jian Zheng ◽  
Yong Qiang Du ◽  
Chun Ming Zhang

Three-dimensional (3D) network structure has been recognized as an efficient approach to enhance the mechanical and thermal conductive properties of polymeric composites. However, it has not been applied in energetic materials. In this work, a fluoropolymer based composite with vertically oriented and interconnected 3D graphite network was fabricated for polymer bonded explosives (PBXs). Here, the graphite and graphene oxide platelets were mixed, and self-assembled via rapid freezing and using crystallized ice as the template. The 3D structure was finally obtained by freezing-dry, and infiltrating with polymer. With the increasing of filler fraction and cooling rate, the thermal conductivity of the polymer composite was significantly improved to 2.15 W m-1 K-1 by 919% than that of pure polymer. Moreover, the mechanical properties, such as tensile strength and elastic modulus, were enhanced by 117% and 563%, respectively, when the highly ordered structure was embedded in the polymer. We attribute the increased thermal and mechanical properties to this 3D network, which is beneficial to the effective heat conduction and force transfer. This study supports a desirable way to fabricate the strong and thermal conductive fluoropolymer composites used for the high-performance polymer bonded explosives (PBXs).


2019 ◽  
Vol 48 (39) ◽  
pp. 14705-14711 ◽  
Author(s):  
Hualin Xiong ◽  
Hongwei Yang ◽  
Caijin Lei ◽  
Pengjiu Yang ◽  
Wei Hu ◽  
...  

Energetic materials, comprising furoxan and 1,2,4-oxadiazole backbones, were synthesized by nitrating 3,3′-bis(5-amino-1,2,4-oxadiazol-3-yl)-4,4′-azofuroxan, followed by cation metathesis, giving compounds with high density, high detonation performance and acceptable sensitivities.


2018 ◽  
Vol 13 (9) ◽  
pp. 1165-1172 ◽  
Author(s):  
Igor L. Dalinger ◽  
Aleksandr V. Kormanov ◽  
Kyrill Yu. Suponitsky ◽  
Nikita V. Muravyev ◽  
Aleksei B. Sheremetev

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