Thermal Decomposition of Organic Peroxides TATP and HMTD by T-Jump/FTIR Spectroscopy

2007 ◽  
Vol 32 (2) ◽  
pp. 127-134 ◽  
Author(s):  
Reiko I. Hiyoshi ◽  
Jun Nakamura ◽  
Thomas B. Brill
Keyword(s):  
Thermal Decomposition ◽  
Ftir Spectroscopy ◽  
Organic Peroxides ◽  
Decomposition Of Organic Peroxides

scholarly journals Prediction of the thermal decomposition of organic peroxides by validated QSPR models

2014 ◽  
Vol 276 ◽  
pp. 216-224 ◽  
Author(s):  
Vinca Prana ◽  
Patricia Rotureau ◽  
Guillaume Fayet ◽  
David André ◽  
Serge Hub ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Organic Peroxides ◽  
Decomposition Of Organic Peroxides

scholarly journals Decomposition of Organic Peroxides

Nature ◽  
1938 ◽  
Vol 141 (3567) ◽  
pp. 472-472 ◽  
Author(s):  
E. J. HARRIS ◽  
A. C. EGERTON
Keyword(s):  
Organic Peroxides ◽  
Decomposition Of Organic Peroxides

Theoretical Study on Thermal Hazardous Properties of C18H10O11 and C18H18O7 Organic Peroxides

2013 ◽  
Vol 787 ◽  
pp. 301-305
Author(s):  
Yun Bo He ◽  
Wei Wang ◽  
Shi Xiong Wang ◽  
Xiang Jun Yang ◽  
Hong Guo
Keyword(s):  
Molecular Structure ◽  
Thermal Decomposition ◽  
Quantum Chemistry ◽  
Organic Compounds ◽  
Theoretical Study ◽  
Organic Peroxides ◽  
Quantum Chemistry Calculation ◽  
The Past ◽  
Chemistry Calculation ◽  
The Stability

The thermal decomposition of organic peroxides are widely used as coagulant for organic compounds, however, its thermal hazardous characteristics have already caused serious accidents in chemical industries, which limited its application in much more strict conditions. Organic peroxides of C18H10O11 and C18H18O7 are two new candidates fitted for industrial explosive. However, as we best known there is little reports available on the geometry structure in the past decades. In this work, by means of quantum chemistry calculation, the relation of safety with molecular structure of C18H10O11 and C18H18O7 are discussed. The molecules with more activity O and the activity part more dispersedly exhibit higher stable, and the configuration has good safety. All the energy of molecule b is higher than that of molecule a. The stability of different configurations are 6a>7a>8a>9a>5a>1a>4a>3a=2a and 1b>7b>5b>6b>4b>2b>3b>8b, respectively, suggesting the structures of 6a,3a,2a,1b,8b exhibit high safety.

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