Concentration‐dependent conformation transition of regenerated silk fibroin induced by graphene oxide nanosheets incorporation

2019 ◽  
Vol 57 (22) ◽  
pp. 1506-1515
Author(s):  
Jin Sha ◽  
Xin Chen ◽  
Liang Ma
2016 ◽  
Vol 8 (5) ◽  
pp. 3349-3358 ◽  
Author(s):  
Chao Zhang ◽  
Yaopeng Zhang ◽  
Huili Shao ◽  
Xuechao Hu

RSC Advances ◽  
2017 ◽  
Vol 7 (6) ◽  
pp. 3108-3116 ◽  
Author(s):  
Chao Zhang ◽  
Yaopeng Zhang ◽  
Jie Luo ◽  
Jingru Shi ◽  
Huili Shao ◽  
...  

The stress–strain curve and proposed model of microstructural change of silk fibroin/GO hybrid fibers during the stretching deformation.


2009 ◽  
Vol 009 (10) ◽  
pp. 1056-1061 ◽  
Author(s):  
Yiming ZHONG ◽  
Yuhong YANG ◽  
Xin CHEN ◽  
Zhengzhong SHAO

2017 ◽  
Vol 898 ◽  
pp. 2214-2223
Author(s):  
Chao Zhang ◽  
Hui Li Shao ◽  
Xue Chao Hu ◽  
Yao Peng Zhang

In order to fabricate high performance artificial silk, hybrid fibers were dry spun from regenerated silk fibroin (RSF) aqueous solution mixed with graphene oxide (GO) nanosheets. The influence of draw ratio on the microstructure and mechanical properties of RSF/GO hybrid fibers was studied through Fourier transform infrared spectroscopy (FT-IR), synchrotron radiation wide-angle X-ray diffraction, Raman spectroscopy and mechanical testing. The results showed that with increasing draw ratio, both amorphous phase and mesophase of the dry-spun artificial fiber gradually converted to crystals. The orientation of crystals and mesophase changed slightly at low draw ratio, but increased significantly at draw ratios of 3 and 4X. The β-sheet content of silk fibroin and the disorder degree of GO sheets in the fibers also increased with the increase of draw ratio. The initial modulus, breaking strength and breaking energy of the hybrid fibers achieved great improvement at a draw ratio of 4X. The structure evolution of the RSF/GO hybrid fibers may benefit the understanding of the structure-property relationship of other composite fibers.


2021 ◽  
Vol 164 ◽  
pp. 105979
Author(s):  
Xin Gao ◽  
Hengwei Zhang ◽  
Erjun Guo ◽  
Fei Yao ◽  
Zengze Wang ◽  
...  

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