scholarly journals Stimuli-responsive polypeptide materials prepared by ring-opening polymerization of α-amino acidN-carboxyanhydrides

2013 ◽  
Vol 51 (7) ◽  
pp. 546-555 ◽  
Author(s):  
Shusheng Zhang ◽  
Zhibo Li
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Stimuli Responsive

scholarly journals Controlled Ring-Opening Polymerization of N-(3-tert-Butoxy-3-oxopropyl) Glycine Derived N-Carboxyanhydrides towards Well-defined Peptoid-based Polyacids

2021 ◽  
Author(s):  
Donghui Zhang ◽  
Bailee Barrett ◽  
Garrett Sternhagen
Keyword(s):  
Carboxylic Acid ◽  
Ring Opening ◽  
Building Blocks ◽  
Ring Opening Polymerization ◽  
Supramolecular Assemblies ◽  
Stimuli Responsive ◽  
Carboxylic Acid Groups

Polypeptoids bearing carboxylic acid groups on the N-substituent are useful building blocks for the construction of peptidomimetic supramolecular assemblies with stimuli-responsive properties. Towards this end, N-(3-tert-butoxy-3-oxopropyl) glycine derived N-carboxyanhydride (tBuO2Pr-NCA)...

Biodegradable stimuli-responsive polypeptide materials prepared by ring opening polymerization

2015 ◽  
Vol 44 (3) ◽  
pp. 612-622 ◽  
Author(s):  
Yong Shen ◽  
Xiaohui Fu ◽  
Wenxin Fu ◽  
Zhibo Li
Keyword(s):  
Ring Opening ◽  
Recent Progress ◽  
Ring Opening Polymerization ◽  
Stimuli Responsive ◽  
The Past

This tutorial review summarizes the most recent progress in stimuli-responsive polypeptides over the past decade.

Amino-functional polyethers: versatile, stimuli-responsive polymers

2020 ◽  
Vol 11 (24) ◽  
pp. 3940-3950 ◽  
Author(s):  
Patrick Verkoyen ◽  
Holger Frey
Keyword(s):  
Ring Opening ◽  
Review Article ◽  
Stimuli Responsive ◽  
New Class ◽  
Stimuli Responsive Polymers ◽  
Responsive Polymers

Amino-functional polyethers have emerged as a new class of “smart”, i.e. pH- and thermoresponsive materials. This review article summarizes the synthesis and applications of these materials, obtained from ring-opening of suitable epoxide monomers.

A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

Bisurea and Bisthiourea H-Bonding Organocatalysts for Ring-Opening Polymerization: Cues for the Catalyst Design

2019 ◽  
Vol 52 (23) ◽  
pp. 9232-9237 ◽  
Author(s):  
Rukshika S. Hewawasam ◽  
U. L. D. Inush Kalana ◽  
Nayanthara U. Dharmaratne ◽  
Thomas J. Wright ◽  
Timothy J. Bannin ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Catalyst Design
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