Electrical conductivity of poly(ethylene terephthalate)/expanded graphite nanocomposites prepared byin situpolymerization

2012 ◽  
Vol 50 (23) ◽  
pp. 1645-1652 ◽  
Author(s):  
S. Paszkiewicz ◽  
A. Szymczyk ◽  
Z. Špitalský ◽  
M. Soccio ◽  
J. Mosnáček ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Ethylene Terephthalate ◽  
Expanded Graphite ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene ◽  
Graphite Nanocomposites

Effect of addition of expanded graphite (EG) on the synthesis and characteristics of poly(ethylene terephthalate) modified with cyclohexanedimethanol (PETG)

Polimery ◽  
2013 ◽  
Vol 58 (11/12) ◽  
pp. 893-899 ◽  
Author(s):  
SANDRA PASZKIEWICZ ◽  
ANNA SZYMCZYK ◽  
ZDENKO SPITALSKY ◽  
JAROSLAV MOSNACEK ◽  
EWA JANUS ◽  
...  
Keyword(s):  
Ethylene Terephthalate ◽  
Expanded Graphite ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene

scholarly journals Electrical, Thermal, and Morphological Properties of Poly(ethylene terephthalate)-Graphite Nanoplatelets Nanocomposites

2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Basheer A. Alshammari ◽  
Arthur N. Wilkinson ◽  
Ghzzai Almutairi
Keyword(s):  
Electrical Conductivity ◽  
Percolation Threshold ◽  
Ethylene Terephthalate ◽  
Threshold Value ◽  
Morphological Properties ◽  
Degree Of Crystallinity ◽  
Graphite Nanoplatelets ◽  
Melt Compounding ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene

Graphite nanoplatelets (GNP) were incorporated with poly(ethylene terephthalate) (PET) matrix by melt-compounding technique using minilab compounder to produce PET-GNP nanocomposites, and then the extruded nanocomposites were compressed using compression molding to obtain films of 1 mm thickness. Percolation threshold value was determined using percolation theory. The electrical conductivity, morphology, and thermal behaviors of these nanocomposites were investigated at different contents of GNP, that is, below, around, and above its percolation threshold value. The results demonstrated that the addition of GNP at loading >5 wt.% made electrically conductive nanocomposites. An excellent electrical conductivity of ~1 S/m was obtained at 15 wt.% of GNP loading. The nanocomposites showed a typical insulator-conductor transition with a percolation threshold value of 5.7 wt.% of GNP. In addition, increasing screw speed enhanced the conductivity of the nanocomposites above its threshold value by ~2.5 orders of magnitude; this behavior is attributed to improved dispersion of these nanoparticles into the PET matrix. Microscopies results exhibited no indication of aggregations at 2 wt.% of GNP; however, some rolling up at 6 wt.% of GNP contents was observed, indicating that a conductive network has been formed, whereas more agglomeration and rolling up could be seen as the GNP content is increased in the PET matrix. These agglomerations reduced their aspect ratio and then reduced their reinforcement efficiency. NP loading (>2 wt.%) increased degree of crystallinity and improved thermal stability of matrix slightly, suggesting that 2 wt.% of GNP is more than enough to nucleate the matrix.

scholarly journals Formation of LIPSS in nanocomposites of Poly (ethylene terephthalate)/Expanded Graphite by using UV nanosecond laser pulses

2016 ◽  
Author(s):  
René I. Rodríguez-Beltrán ◽  
Margarita Hernandez ◽  
Tiberio A. Ezquerra ◽  
Sandra Paszkiewicz ◽  
Anna Szymczyk ◽  
...  
Keyword(s):  
Ethylene Terephthalate ◽  
Expanded Graphite ◽  
Laser Pulses ◽  
Nanosecond Laser ◽  
Poly Ethylene Terephthalate ◽  
Nanosecond Laser Pulses ◽  
Poly Ethylene
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