Nanoconfinement as a tool to study early stages of polymer crystallization

2008 ◽  
Vol 46 (15) ◽  
pp. 1556-1561 ◽  
Author(s):  
Mario Beiner
Keyword(s):  
Polymer Crystallization ◽  
Early Stages

scholarly journals Heterogeneous directional mobility in the early stages of polymer crystallization

2008 ◽  
Vol 128 (1) ◽  
pp. 014903 ◽  
Author(s):  
Naida Lacevic ◽  
Laurence E. Fried ◽  
Richard H. Gee
Keyword(s):  
Polymer Crystallization ◽  
Early Stages

Early stages of polymer crystallization—a dielectric study

Polymer ◽  
2003 ◽  
Vol 44 (24) ◽  
pp. 7467-7476 ◽  
Author(s):  
Andreas Wurm ◽  
Ragab Soliman ◽  
Christoph Schick
Keyword(s):  
Polymer Crystallization ◽  
Dielectric Study ◽  
Early Stages

Revival of the Induction Time Concept in the Theory of Polymer Crystallization

1993 ◽  
Vol 58 (10) ◽  
pp. 2444-2450 ◽  
Author(s):  
František Lednický ◽  
Miroslava Muchová
Keyword(s):  
Induction Time ◽  
Isothermal Crystallization ◽  
Polymer Crystallization ◽  
Dispersed Phase ◽  
Carbon Fibres ◽  
Early Stages ◽  
Spherulite Growth ◽  
Microscopical Method

To monitor early stages of spherulite growth, a microscopical method has been worked out based on the photometrical measurement of the intensity of depolarized light during isothermal crystallization. Application of the technique to polypropylene yields the evidence of existence of nucleation induction time which reflects the processes taking place prior to the onset of spherulite growth, viz. the formation of stable crystal nuclei. Using the method, it is possible to evaluate also systems with a dispersed phase, the interfacial relations being reflected in the induction time of the nucleation on the surface of the dispersed phase. Application to the model PP/carbon fibres system yields differing results for carbon fibres of various provenance and of various properties.

Spherulitic crystal growth in the prodissoconch larval of Crassostrea virginica

1983 ◽  
Vol 41 ◽  
pp. 518-519
Author(s):  
George G. Cocks ◽  
Louis Leibovitz ◽  
DoSuk D. Lee
Keyword(s):  
Crystal Structure ◽  
Crassostrea Virginica ◽  
Crystal Orientation ◽  
Developmental Changes ◽  
Gastrula Stage ◽  
Orthorhombic Crystal ◽  
Orthorhombic Crystal Structure ◽  
Stages Of Growth ◽  
Early Stages ◽  
Initial Deposition

Our understanding of the structure and the formation of inorganic minerals in the bivalve shells has been considerably advanced by the use of electron microscope. However, very little is known about the ultrastructure of valves in the larval stage of the oysters. The present study examines the developmental changes which occur between the time of conception to the early stages of Dissoconch in the Crassostrea virginica(Gmelin), focusing on the initial deposition of inorganic crystals by the oysters.The spawning was induced by elevating the temperature of the seawater where the adult oysters were conditioned. The eggs and sperm were collected separately, then immediately mixed for the fertilizations to occur. Fertilized animals were kept in the incubator where various stages of development were stopped and observed. The detailed analysis of the early stages of growth showed that CaCO3 crystals(aragonite), with orthorhombic crystal structure, are deposited as early as gastrula stage(Figuresla-b). The next stage in development, the prodissoconch, revealed that the crystal orientation is in the form of spherulites.

Formation of Dislocation Channels in Neutron Irradiated Molybdenum

1972 ◽  
Vol 30 ◽  
pp. 672-673
Author(s):  
S. Mahajan
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Ambient Temperature ◽  
Room Temperature ◽  
Channel Formation ◽  
Early Stages ◽  
Transmission Electron ◽  
Three Stages ◽  
Two Stages ◽  
Polycrystalline Molybdenum

The evolution of dislocation channels in irradiated metals during deformation can be envisaged to occur in three stages: (i) formation of embryonic cluster free regions, (ii) growth of these regions into microscopically observable channels and (iii) termination of their growth due to the accumulation of dislocation damage. The first two stages are particularly intriguing, and we have attempted to follow the early stages of channel formation in polycrystalline molybdenum, irradiated to 5×1019 n. cm−2 (E > 1 Mev) at the reactor ambient temperature (∼ 60°C), using transmission electron microscopy. The irradiated samples were strained, at room temperature, up to the macroscopic yield point.Figure 1 illustrates the early stages of channel formation. The observations suggest that the cluster free regions, such as A, B and C, form in isolated packets, which could subsequently link-up to evolve a channel.

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