Payne effect in silica-filled styrene–butadiene rubber: Influence of surface treatment

2006 ◽  
Vol 45 (3) ◽  
pp. 286-298 ◽  
Author(s):  
J. Ramier ◽  
C. Gauthier ◽  
L. Chazeau ◽  
L. Stelandre ◽  
L. Guy
Keyword(s):  
Surface Treatment ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Payne Effect ◽  
Styrene Butadiene

scholarly journals Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds

2020 ◽  
Vol 39 (1) ◽  
pp. 81-90
Author(s):  
An Zhao ◽  
Xuan-Yu Shi ◽  
Shi-Hao Sun ◽  
Hai-Mo Zhang ◽  
Min Zuo ◽  
...  
Keyword(s):  
Carbon Black ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Payne Effect ◽  
Rubber Compounds ◽  
Styrene Butadiene

Effect of Hydrocarbon and Amine Diluents on the Properties of Dicumyl Peroxide Cured Styrene-Butadiene Rubber, Part I: Gum Compositions

1995 ◽  
Vol 68 (2) ◽  
pp. 212-218 ◽  
Author(s):  
Gary R. Hamed ◽  
Jing-Ming Hsu
Keyword(s):  
Storage Modulus ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Dicumyl Peroxide ◽  
Butadiene Rubber ◽  
Payne Effect ◽  
Rubber Part ◽  
Strain Storage ◽  
Strength And Stiffness ◽  
Styrene Butadiene

Abstract Gum SBR compositions containing dicumyl peroxide and either alkane (nonadecane) or amine (octadecylamine or oleylamine) diluent were prepared. Dilution caused a reduction in rheometer torque upon curing and in the resulting crosslink density based on solvent swelling. Results for each diluent were indistinguishable. However, tensile strengths and especially storage moduli were different for nonadecane- and octadecylamine-diluted vulcanizates. Added octadecylamine mildly reinforced the gum, while nonadecane lowered strength and stiffness. Furthermore, quite strikingly, octadecylamine-diluted samples had a large, low-strain storage modulus, which decreased markedly with strain amplitude (Payne effect), while vulcanizates diluted with nonadecane showed no Payne effect.

Influence of Powder Surface Treatment on the Dispersion Behavior of Silica into Polymeric Materials

2002 ◽  
Vol 75 (4) ◽  
pp. 725-737 ◽  
Author(s):  
Alberto Scurati ◽  
Ica Manas-Zloczower ◽  
Donald L. Feke
Keyword(s):  
Surface Treatment ◽  
Coupling Agent ◽  
Polymeric Materials ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Powder Surface ◽  
Precipitated Silica ◽  
Controlled Flow ◽  
Styrene Butadiene ◽  
Effect Of Surface

Abstract The effect of surface treatment on silica agglomerate dispersibility was investigated. Precipitated silica powders were treated with a commercially available coupling agent Bis-(triethoxysilylpropyl)-tetrasulphane (TESPT) in a blender. Spherical agglomerates of known density were prepared and dispersed in styrene butadiene rubber (SBR) under controlled flow conditions. The erosion kinetics was monitored by measuring the reduction in size of parent agglomerate with time. Silica dispersibility was greatly enhanced upon surface treatment. The coupling agent used in surface treatment is known to reduce filler—filler interactions and therefore affects the intrinsic cohesivity of the powder. However powder surface treatment can also induce changes in agglomerate morphology and filler-liquid interactions. The work presented in this paper evidences such changes.

Payne effect of silica-filled styrene-butadiene rubber

Polymer ◽  
2017 ◽  
Vol 116 ◽  
pp. 304-313 ◽  
Author(s):  
Ruiquan Yang ◽  
Yihu Song ◽  
Qiang Zheng
Keyword(s):  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Payne Effect ◽  
Styrene Butadiene

EFFECTS OF MIXING PARAMETERS AND THEIR INTERACTIONS ON PROPERTIES OF CARBON BLACK FILLED STYRENE-BUTADIENE RUBBER

2018 ◽  
Vol 91 (3) ◽  
pp. 521-536 ◽  
Author(s):  
Jirawat Narongthong ◽  
Pongdhorn Sae-Oui ◽  
Chakrit Sirisinha
Keyword(s):  
Fill Factor ◽  
Mixing Time ◽  
Filler Loading ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Dispersion Index ◽  
Rotor Speed ◽  
Payne Effect ◽  
Mixing Parameters ◽  
Styrene Butadiene

ABSTRACT The effects of various mixing parameters on state-of-mix and vulcanizate properties of carbon black filled styrene-butadiene rubber prepared by an intermeshing-rotor internal mixer were observed. The parameters studied include mixing time, rotor speed, fill factor, and filler loading. The interactions between these parameters are also focused. To do this, the mixing parameters are changed simultaneously, and the data are analyzed using response surface methodology. Results reveal that the dispersion index, Payne effect, and tensile properties are not linearly related to mixing time and filler loading but are linearly related to rotor speed and fill factor. The effect of mixing time on dispersion index and Payne effect depends strongly on the levels of rotor speed and filler loading. Increasing the rotor speed or filler loading reduces the effect of mixing time on dispersion index and, thus, on the Payne effect. Among the four parameters, filler loading shows the strongest effect on tensile strength (TS) and modulus at 100% elongation (M100). In addition, the effect of filler loading on the tensile properties depends mainly on the levels of mixing time and fill factor, for example, increasing of fill factor reduces the effect of filler loading on both TS and M100.

Effects of White Rot Fungus Physisporinus sp., Isolated in Japan, on Styrene-butadiene Rubber

2020 ◽  
Vol 93 (9) ◽  
pp. 289-292
Author(s):  
Yumi SHIMIZU ◽  
Shuma SATHO ◽  
Taro NAKAJIMA ◽  
Hiroaki KOUZAI ◽  
Kiminori SHIMIZU
Keyword(s):  
White Rot ◽  
White Rot Fungus ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Styrene Butadiene
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