Structural and transport characteristics of polyethylene oxide/phenolic resin blend solid polymer electrolytes

2004 ◽  
Vol 42 (21) ◽  
pp. 3866-3875 ◽  
Author(s):  
Peter P. Chu ◽  
M. Jaipal Reddy ◽  
Joyce Tsai
Keyword(s):  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Phenolic Resin ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Influence of Nano Filler (ZrO2) on Optical and Thermal Studies of Potassium Doped Polyethylene Oxide Solid Polymer Electrolytes

2022 ◽  
Vol 1048 ◽  
pp. 101-109
Author(s):  
Suresh Sripada ◽  
M. Chandrashekhar Reddy ◽  
T. Sreekanth ◽  
Rajesh Siripuram ◽  
K. Venkateshwarlu
Keyword(s):  
Optical Absorption ◽  
Band Gap ◽  
Polymer Electrolyte ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Optical Band Gap ◽  
Thermal Studies ◽  
Fundamental Absorption Edge ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Solid polymer electrolyte films made with potassium doped Polyethylene oxide using ZrO2 as nanofiller (70PEO-30KBF4-x ZrO2 where x = 1, 2.5, 5, 7.5, & 10 wt% ­­) were prepared by solution casting technique. Optical and thermal properties of polymer electrolyte films were studied by using Optical absorption and DSC techniques. From Optical absorption spectra, it is observed that fundamental absorption edge is shifted towards the higher wavelength side (range 259- 297 nm) with increase of nano filler (ZrO­2) concentration (1-10 wt %). Optical band gap for all electronic transitions (p=1/2, 2, 2/3 and 1/3) are found to be increased as incorporation of nano filler (ZrO2) which confirms the structural rearrangements takes place in polymer electrolyte films. Optical band gap for indirect allowed transitions (p=1/2) are found to be in the range of 1.93-3.34eV. Decrease in Urbach energy (4.8eV- 1.4eV) is associated with decrease in defect formation in host polymeric matrix (PEO-KBF4) as a result of embedded nano filler (ZrO2). DSC spectra analysis of polymer electrolytes has showed melting temperatures in the range 63.63-73.71°C and highest crystallinity is found to be 85 % (10 wt % ZrO­2). Enthalpy values are elevated with increase in nanofiller composition (ZrO2) in the present polymer electrolyte films.Keywords: PEO based polymer electrolytes, Solid polymer electrolytes, Optical and Thermal studies.

Nanocomposite solid polymer electrolytes based on polyethylene oxide, modified nanoclay, and tetraethylammonium tetrafluoroborate for application in solid-state supercapacitor

2015 ◽  
Vol 55 (7) ◽  
pp. 1536-1545 ◽  
Author(s):  
Patchaiyappan Sivaraman ◽  
Kannakaje Shashidhara ◽  
Avinash P. Thakur ◽  
Asit B. Samui ◽  
Arup R. Bhattacharyya
Keyword(s):  
Solid State ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Polyethylene Oxide (PEO)-Based Solid Polymer Electrolytes for Rechargeable Lithium-Ion Batteries

2021 ◽  
pp. 57-80
Author(s):  
Prasanth Raghavan ◽  
P. P. Abhijith ◽  
N. S. Jishnu ◽  
Akhila Das ◽  
Neethu T. M. Balakrishnan ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

scholarly journals Effect of X-ray Irradiation on Dielectric Properties of Polymer Electrolytes Complexed with LiCF3SO3

2014 ◽  
Vol 17 (3) ◽  
pp. 139-145 ◽  
Author(s):  
C. Vijil Vani ◽  
S. Thanikaikarasan ◽  
T. Mahalingam ◽  
P. J. Sebastian ◽  
L. E. Verea ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Lithium Salt ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Frequency Range ◽  
Lithium Ions ◽  
X Ray ◽  
The Given

Solid polymer electrolytes of polyethylene oxide (PEO) embedded with LiCF3SO3 was prepared and subjected to X-ray irradiation of different dosages (1.5 to 6 Gy). Ionic conductivity and dielectric studies were made over a frequency range of 100 Hz to 490 KHz. A little increase in ionic conductivity was noted for the sample irradiated for 1.5 Gy and the equivalent circuit remained unaltered for irradiated samples. Remarkable increase in dielectric constant was found for the irradiated samples. It was found that irradiation improved the dissolution of lithium salt and increased the polymer/Lithium interaction and thus improved the polarizability of the electrolyte. The frequency of hopping and liberation of free lithium ions were found altered by irradiation and hence the given dosage was found to have an optimum value in concern with the ionic conductivity of the electrolyte.

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