How does the type of counterion influence the polymerization rate and thermal properties of tailored choline-based linear- and star-shaped poly(ionic liquid)s PILs?

2018 ◽  
Vol 56 (23) ◽  
pp. 2681-2691 ◽  
Author(s):  
Paulina Maksym ◽  
Magdalena Tarnacka ◽  
Kamila Wolnica ◽  
Andrzej Dzienia ◽  
Andrzej Zięba ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Thermal Properties ◽  
Polymerization Rate ◽  
Poly Ionic Liquid

Cellulosic poly(ionic liquid)s: synthesis, characterization and application in the cycloaddition of CO2 to epoxides

RSC Advances ◽  
2015 ◽  
Vol 5 (55) ◽  
pp. 44598-44603 ◽  
Author(s):  
Qin Chen ◽  
Chang Peng ◽  
Haibo Xie ◽  
Zongbao kent Zhao ◽  
Ming Bao
Keyword(s):  
Ionic Liquid ◽  
Thermal Properties ◽  
Nucleophilic Substitution ◽  
Cellulosic Materials ◽  
Methyl Imidazole ◽  
Poly Ionic Liquid

Cellulosic poly(ionic liquid)s were prepared via nucleophilic substitution of chlorinated cellulose by 1-methyl-imidazole and their structure and thermal properties have been characterized, which were ready for the preparation of novel cellulosic materials.

A Novel Poly(Ionic Liquid) as the Thermal Insulating Material

2020 ◽  
Vol 13 (3) ◽  
pp. 241-247
Author(s):  
Wenxin Wei ◽  
Guifeng Ma ◽  
Hongtao Wang ◽  
Jun Li
Keyword(s):  
Thermal Conductivity ◽  
Ionic Liquid ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Flame Resistance ◽  
Insulating Material ◽  
Low Thermal Conductivity ◽  
Thermal Insulating ◽  
Poly Ionic Liquid

Objective: A new poly(ionic liquid)(PIL), poly(p-vinylbenzyltriphenylphosphine hexafluorophosphate) (P[VBTPP][PF6]), was synthesized by quaternization, anion exchange reaction, and free radical polymerization. Then a series of the PIL were synthesized at different conditions. Methods: The specific heat capacity, glass-transition temperature and melting temperature of the synthesized PILs were measured by differential scanning calorimeter. The thermal conductivities of the PILs were measured by the laser flash analysis method. Results: Results showed that, under optimized synthesis conditions, P[VBTPP][PF6] as the thermal insulator had a high glass-transition temperature of 210.1°C, high melting point of 421.6°C, and a low thermal conductivity of 0.0920 W m-1 K-1 at 40.0°C (it was 0.105 W m-1 K-1 even at 180.0°C). The foamed sample exhibited much low thermal conductivity λ=0.0340 W m-1 K-1 at room temperature, which was comparable to a commercial polyurethane thermal insulating material although the latter had a much lower density. Conclusion: In addition, mixing the P[VBTPP][PF6] sample into polypropylene could obviously increase the Oxygen Index, revealing its efficient flame resistance. Therefore, P[VBTPP][PF6] is a potential thermal insulating material.

Modular Platform for Synthesis of Poly(Ionic Liquid) Electrolytes for Electrochemical Applications in Supercapacitors

2021 ◽  
Vol 6 (15) ◽  
pp. 3795-3801
Author(s):  
Radostina Kalinova ◽  
Ivaylo Dimitrov ◽  
Christo Novakov ◽  
Svetlana Veleva ◽  
Antonia Stoyanova
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrolytes ◽  
Electrochemical Applications ◽  
Modular Platform ◽  
Poly Ionic Liquid

Facile fabrication of self-reporting micellar and vesicular structures based on etching-ion exchange strategy of photonic composite spheres of poly(ionic liquid)

Nanoscale ◽  
2021 ◽  
Author(s):  
Ning Gao ◽  
Kang Zhou ◽  
Kai Feng ◽  
Wanlin Zhang ◽  
Jiecheng Cui ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ion Exchange ◽  
Chemical Environment ◽  
Facile Fabrication ◽  
Poly Ionic Liquid

Micellar and vesicular structures capable of sensing and reporting the chemical environment as well as facilely introducing user-defined functions make a vital contribution to constructing versatile compartmentalized systems. Herein, combing...

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