Synthesis of poly(3-hexylthiophene)-block -poly(ethylene)-block -poly(3-hexylthiophene) via a combination of ring-opening olefin metathesis polymerization and grignard metathesis polymerization

2013 ◽  
Vol 51 (18) ◽  
pp. 3810-3817 ◽  
Author(s):  
Songsu Kang ◽  
Robert J. Ono ◽  
Christopher W. Bielawski
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Metathesis Polymerization ◽  
Poly Ethylene

End Capping Ring-Opening Olefin Metathesis Polymerization Polymers with Vinyl Lactones

2008 ◽  
Vol 130 (33) ◽  
pp. 11040-11048 ◽  
Author(s):  
Stefan Hilf ◽  
Robert H. Grubbs ◽  
Andreas F. M. Kilbinger
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Metathesis Polymerization ◽  
End Capping

scholarly journals Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

2019 ◽  
Vol 15 ◽  
pp. 310-332 ◽  
Author(s):  
Patrycja Żak ◽  
Cezary Pietraszuk
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Polymeric Materials ◽  
Acyclic Diene Metathesis ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Cross Metathesis ◽  
Terminal Olefins ◽  
Synthesized Materials

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.

Living Ring-Opening Olefin Metathesis Polymerization

2008 ◽  
pp. 2-71 ◽  
Author(s):  
Grinne Black ◽  
Declan Maher ◽  
Wilhelm Risse
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Metathesis Polymerization
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