Crystal-liquid crystal ordered double layer electroactive polymer prepared with phase transition sequential polymerization, showing metallic electrochromism-bronze, silver, and gold

2013 ◽  
Vol 51 (15) ◽  
pp. 3097-3102 ◽  
Author(s):  
Hiromasa Goto
2017 ◽  
Author(s):  
Niamh Mac Fhionnlaoich ◽  
Stephen Schrettl ◽  
Nicholas B. Tito ◽  
Ye Yang ◽  
Malavika Nair ◽  
...  

The arrangement of nanoscale building blocks into patterns with microscale periodicity is challenging to achieve via self-assembly processes. Here, we report on the phase transition-driven collective assembly of gold nanoparticles in a thermotropic liquid crystal. A temperature-induced transition from the isotropic to the nematic phase leads to the assembly of individual nanometre-sized particles into arrays of micrometre-sized aggregates, whose size and characteristic spacing can be tuned by varying the cooling rate. This fully reversible process offers hierarchical control over structural order on the molecular, nanoscopic, and microscopic level and is an interesting model system for the programmable patterning of nanocomposites with access to micrometre-sized periodicities.


2002 ◽  
Vol 80 (8) ◽  
pp. 1162-1165 ◽  
Author(s):  
B Henrissat ◽  
G K Hamer ◽  
M G Taylor ◽  
R H Marchessault

A series of dodecyl 1-thio-β-D-glycosides has been synthesized and characterized (DSC, NMR, CP MAS, X-ray diffraction) as possible new marking materials with liquid-crystalline properties. These compounds undergo solid to liquid crystal phase transitions at various temperatures, which depend on the nature of the carbohydrate part of the structure. Their liquid-crystalline phases show extreme shear thinning behaviour.Key words: liquid crystal, powder X-ray diffraction, phase transition, thioglycoside, solid-state NMR, marking material


2021 ◽  
pp. 117015
Author(s):  
A. Farinha ◽  
F.C. Flores ◽  
A.R. Sampaio ◽  
N.M. Kimura ◽  
F.C.M. Freire

2011 ◽  
Vol 84 (4) ◽  
Author(s):  
Chandra Shekhar Pati Tripathi ◽  
Patricia Losada-Pérez ◽  
Christ Glorieux ◽  
Alexandra Kohlmeier ◽  
Maria-Gabriela Tamba ◽  
...  

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