Synthesis of PNIPAM polymer brushes on reduced graphene oxide based on click chemistry and RAFT polymerization

2011 ◽  
Vol 50 (2) ◽  
pp. 329-337 ◽  
Author(s):  
Yongfang Yang ◽  
Xiaohui Song ◽  
Liang Yuan ◽  
Mao Li ◽  
Jinchuan Liu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Click Chemistry ◽  
Reduced Graphene Oxide ◽  
Polymer Brushes ◽  
Raft Polymerization ◽  
Reduced Graphene

scholarly journals CO2 Capture by Reduced Graphene Oxide Monoliths with Incorporated CeO2 Grafted with Functionalized Polymer Brushes

2021 ◽  
Vol 11 (23) ◽  
pp. 11154
Author(s):  
Nikolaos Politakos ◽  
Luis Serrano Cantador ◽  
Juan Antonio Cecilia ◽  
Iranzu Barbarin ◽  
Radmila Tomovska
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Polymer Brushes ◽  
Structural Changes ◽  
Co2 Adsorption ◽  
Raft Polymerization ◽  
Trimethylammonium Chloride ◽  
Reversible Addition ◽  
Reduced Graphene ◽  
Adsorption Of Co2

The monolithic materials of reduced graphene oxide (rGO) can be used successfully in CO2 adsorption. Here, the incorporation of CeO2 particles with and without polymer brushes grafted from the particles showed that the structural properties could be changed, affecting the adsorption of CO2. Polymer brushes of (1) poly(acrylic acid) (PAA), (2) poly(vinyl caprolactam) (PVCL) and (3) poly[(2-(methacryloyloxy)ethyl) trimethylammonium chloride] (PMETAC) were grafted from CeO2 via reversible addition−fragmentation chain transfer (RAFT) polymerization. The preparation of monoliths of rGO with different modified CeO2 particles led to different thermal properties (TGA), structural changes (BET isotherms) and CO2 adsorption. The responsive character of the CeO2@polymer was proven by the DLS and UV results. The responsive character of the particles incorporated into the rGO monolith affected not only the adsorption capacity but also the microstructure and values of the surface volume of the pores of the monolith. Monoliths with porosity values for better adsorption were affected by the responsive character of the polymer.

Fabrication CdS nanoparticles on the edges of reduced graphene oxide sheets with P2VP polymer brushes

2014 ◽  
Vol 118 ◽  
pp. 184-187 ◽  
Author(s):  
Yongfang Yang ◽  
Mao Li ◽  
Yulei Xie ◽  
Xiaohui Song ◽  
Xiongwei Qu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Polymer Brushes ◽  
Cds Nanoparticles ◽  
Reduced Graphene ◽  
Graphene Oxide Sheets

scholarly journals “Click” Chemistry on Gold Electrodes Modified with Reduced Graphene Oxide by Electrophoretic Deposition

Surfaces ◽  
2019 ◽  
Vol 2 (1) ◽  
pp. 193-204 ◽  
Author(s):  
Vladyslav Mishyn ◽  
Patrik Aspermair ◽  
Yann Leroux ◽  
Henri Happy ◽  
Wolfgang Knoll ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Click Chemistry ◽  
Reduced Graphene Oxide ◽  
Electrophoretic Deposition ◽  
Potassium Ferrocyanide ◽  
Gold Electrodes ◽  
Redox Mediators ◽  
Sensing Platforms ◽  
Reduced Graphene ◽  
Vapor Treatment

The coating of electrical interfaces with reduced graphene oxide (rGO) films and their subsequent chemical modification are essential steps in the fabrication of graphene-based sensing platforms. In this work, electrophoretic deposition (EPD) of graphene oxide at 2.5 V for 300 s followed by vapor treatment were employed to coat gold electrodes uniformly with rGO. These interfaces showed excellent electron transfer characteristics for redox mediators such as ferrocene methanol and potassium ferrocyanide. Functional groups were integrated onto the Au/rGO electrodes by the electro-reduction of an aryldiazonium salt, 4-((triisopropylsilyl)ethylenyl)benzenediazonium tetrafluoroborate (TIPS-Eth-ArN) in our case. Chemical deprotection of the triisopropylsilyl function resulted in propargyl-terminated Au/rGO electrodes to which azidomethylferrocene was chemically linked using the Cu(I) catalyzed “click” chemistry.

Cu(0) nanoparticle-decorated functionalized reduced graphene oxide sheets as artificial peroxidase enzymes: application for colorimetric detection of Cr(vi) ions

2019 ◽  
Vol 43 (3) ◽  
pp. 1404-1414 ◽  
Author(s):  
Priyakshree Borthakur ◽  
Purna K. Boruah ◽  
Manash R. Das ◽  
Sabine Szunerits ◽  
Rabah Boukherroub
Keyword(s):  
Graphene Oxide ◽  
Click Chemistry ◽  
Reduced Graphene Oxide ◽  
Colorimetric Detection ◽  
Reduced Graphene ◽  
Peroxidase Enzymes ◽  
Graphene Oxide Sheets

Graphene oxide sheets were functionalized by a “click” chemistry approach which was utilized for the decoration of Cu(0) nanoparticles for sensitive colorimetric detection of Cr(vi) ions.

Nitrogen-doped graphene stabilized copper nanoparticles for Huisgen [3+2] cycloaddition “click” chemistry

2019 ◽  
Vol 55 (44) ◽  
pp. 6249-6252 ◽  
Author(s):  
R. V. Siva Prasanna Sanka ◽  
Balaji K. ◽  
Yves Leterrier ◽  
Shyam Pandey ◽  
Monika Srivastava ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Click Chemistry ◽  
Reduced Graphene Oxide ◽  
Heterogeneous Catalyst ◽  
Copper Nanoparticles ◽  
Nitrogen Doped ◽  
Reduced Graphene ◽  
Nitrogen Doped Graphene ◽  
Doped Graphene

N-doped reduced graphene oxide stabilized copper nanoparticles are designed as a heterogeneous catalyst for achieving Cu(i)-catalyzed [3+2] cycloaddition “click” chemistry.

High Toughness Inorganic Solid Electrolytes via the Use of Reduced Graphene-Oxide

2020 ◽  
Author(s):  
Christos E. Athanasiou ◽  
Mok Yun Jin ◽  
Cristina Ramirez ◽  
Nitin P. Padture ◽  
Brian W. Sheldon
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Solid Electrolytes ◽  
High Toughness ◽  
Reduced Graphene
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