Aqueous MADIX/RAFT polymerization of diallyldimethylammonium chloride: Extension to the synthesis of poly(DADMAC)-based double hydrophilic block copolymers

2010 ◽  
Vol 48 (22) ◽  
pp. 5163-5171 ◽  
Author(s):  
Mathias Destarac ◽  
Aymeric Guinaudeau ◽  
Roland Geagea ◽  
Stephane Mazieres ◽  
Eric Van Gramberen ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Raft Polymerization ◽  
Diallyldimethylammonium Chloride ◽  
Double Hydrophilic Block Copolymers

Aggregation behavior of double hydrophilic block copolymers in aqueous media

2019 ◽  
Vol 276 ◽  
pp. 47-56 ◽  
Author(s):  
Mehul Khimani ◽  
Shin-ichi Yusa ◽  
V.K. Aswal ◽  
P. Bahadur
Keyword(s):  
Block Copolymers ◽  
Aqueous Media ◽  
Aggregation Behavior ◽  
Double Hydrophilic Block Copolymers

One-step synthesis of poly(2-oxazoline)-based amphiphilic block copolymers using a dual initiator for RAFT polymerization and CROP

Polymer ◽  
2014 ◽  
Vol 55 (23) ◽  
pp. 5986-5990 ◽  
Author(s):  
Young Chang Yu ◽  
Hang Sung Cho ◽  
Woong-Ryeol Yu ◽  
Ji Ho Youk
Keyword(s):  
Block Copolymers ◽  
Raft Polymerization ◽  
Amphiphilic Block Copolymers ◽  
One Step

Solvent Effects on the Synthesis of Polymeric Nanoparticles via Block Copolymer Self-Assembly Using Microporous Membranes

2020 ◽  
Vol 1000 ◽  
pp. 324-330
Author(s):  
Sri Agustina ◽  
Masayoshi Tokuda ◽  
Hideto Minami ◽  
Cyrille Boyer ◽  
Per B. Zetterlund
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Self Assembly ◽  
Polymeric Nanoparticles ◽  
Raft Polymerization ◽  
Membrane Emulsification ◽  
Membrane Pore ◽  
Novel Technique ◽  
Wide Range ◽  
Membrane Pore Size

The self-assembly of block copolymers has attracted attention for many decades because it can yield polymeric nanoobjects with a wide range of morphologies. Membrane emulsification is a fairly novel technique for preparation of various types of emulsions, which relies on the dispersed phase passing through a membrane in order to effect droplet formation. In this study, we have prepared polymeric nanoparticles of different morphologies using self-assembly of asymmetric block copolymers in connection with membrane emulsification. Shirasu Porous Glass (SPG) membranes has been employed as the membrane emulsification equipment, and poly (oligoethylene glycol acrylate)-block-poly (styrene) (POEGA-b-PSt) copolymers prepared via RAFT polymerization. It has been found that a number of different morphologies can be achieved using this novel technique, including spheres, rods, and vesicles. Interestingly, the results have shown that the morphology can be controlled not only by adjusting experimental parameters specific to the membrane emulsification step such as membrane pore size and pressure, but also by changing the nature of organic solvent. As such, this method provides a novel route to these interesting nanoobjects, with interesting prospects in terms of exercising morphology control without altering the nature of the block copolymer itself.

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