Photopolymerization of poly(ethylene glycol) dimethacrylates: The influence of ionic liquids on the formulation and the properties of the resultant polymer materials

2010 ◽  
Vol 48 (11) ◽  
pp. 2388-2409 ◽  
Author(s):  
Sergey A. Chesnokov ◽  
Marya Yu. Zakharina ◽  
Alexander S. Shaplov ◽  
Elena I. Lozinskaya ◽  
Inna A. Malyshkina ◽  
...  
2021 ◽  
Vol 9 (8) ◽  
pp. 4679-4686
Author(s):  
Coby J. Clarke ◽  
Richard P. Matthews ◽  
Alex P. S. Brogan ◽  
Jason P. Hallett

Gels prepared from metal containing ionic liquids with cross-linked poly(ethylene glycol) have surface compositions and mechanical properties that can be controlled by Lewis basicity and acidity of the metal species.


2008 ◽  
Vol 10 (2) ◽  
pp. 248-250 ◽  
Author(s):  
Chuan Wu ◽  
Jiajian Peng ◽  
Jiayun Li ◽  
Ying Bai ◽  
Yingqian Hu ◽  
...  

Micromachines ◽  
2020 ◽  
Vol 11 (3) ◽  
pp. 246 ◽  
Author(s):  
Max Männel ◽  
Carolin Fischer ◽  
Julian Thiele

Three-dimensional (3D) printing of microfluidic devices continuously replaces conventional fabrication methods. A versatile tool for achieving microscopic feature sizes and short process times is micro-stereolithography (µSL). However, common resins for µSL lack biocompatibility and are cytotoxic. This work focuses on developing new photo-curable resins as a basis for µSL fabrication of polymer materials and surfaces for cell culture. Different acrylate- and methacrylate-based compositions are screened for material characteristics including wettability, surface roughness, and swelling behavior. For further understanding, the impact of photo-absorber and photo-initiator on the cytotoxicity of 3D-printed substrates is studied. Cell culture experiments with human umbilical vein endothelial cells (HUVECs) in standard polystyrene vessels are compared to 3D-printed parts made from our library of homemade resins. Among these, after optimizing material composition and post-processing, we identify selected mixtures of poly(ethylene glycol) diacrylate (PEGDA) and poly(ethylene glycol) methyl ethyl methacrylate (PEGMEMA) as most suitable to allow for fabricating cell culture platforms that retain both the viability and proliferation of HUVECs. Next, our PEGDA/PEGMEMA resins will be further optimized regarding minimal feature size and cell adhesion to fabricate microscopic (microfluidic) cell culture platforms, e.g., for studying vascularization of HUVECs in vitro.


2006 ◽  
Vol 7 (7) ◽  
pp. 692-698 ◽  
Author(s):  
Kazunori Nakashima ◽  
Jun Okada ◽  
Tatsuo Maruyama ◽  
Noriho Kamiya ◽  
Masahiro Goto

2012 ◽  
Vol 52 (7) ◽  
pp. 494-498 ◽  
Author(s):  
E. M. Erdni-Goryaev ◽  
A. Yu. Alent’ev ◽  
N. A. Belov ◽  
D. O. Ponkratov ◽  
A. S. Shaplov ◽  
...  

2014 ◽  
Vol 38 (12) ◽  
pp. 6133-6138 ◽  
Author(s):  
Martina Maya Cecchini ◽  
Anissa Bendjeriou ◽  
Najib Mnasri ◽  
Clarence Charnay ◽  
Francesco De Angelis ◽  
...  

The syntheses of ten novel mono-, di- or tri-cationic poly(ethylene glycol)-based ionic liquids (ILPEGs), incorporating tetra-substituted ammonium cations, are described.


2004 ◽  
Vol 16 (16) ◽  
pp. 3091-3097 ◽  
Author(s):  
Marc A. Klingshirn ◽  
Scott K. Spear ◽  
Raman Subramanian ◽  
John D. Holbrey ◽  
Jonathan G. Huddleston ◽  
...  

2010 ◽  
Vol 2 (3) ◽  
pp. 870-876 ◽  
Author(s):  
Meirong Cai ◽  
Yongmin Liang ◽  
Meihuan Yao ◽  
Yanqiu Xia ◽  
Feng Zhou ◽  
...  

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