Anionic polymerization of methacrylates by samarium (III) enolate on networked polystyrene: Effects of its sterically confined environment on polymerization behavior

2009 ◽  
Vol 47 (6) ◽  
pp. 1510-1521
Author(s):  
Daisuke Nagai ◽  
Asuka Fujii ◽  
Masayoshi Tanaka ◽  
Bungo Ochiai ◽  
Atsushi Sudo ◽  
...  
Keyword(s):  
Anionic Polymerization ◽  
Polymerization Behavior ◽  
Confined Environment

Anionic Polymerization Behavior of α-Methylene-N -methylpyrrolidone

2013 ◽  
Vol 323 (1) ◽  
pp. 86-91 ◽  
Author(s):  
Takashi Ishizone ◽  
Keita Kitazawa ◽  
Takashi Suzuki ◽  
Susumu Kawauchi
Keyword(s):  
Anionic Polymerization ◽  
Polymerization Behavior

scholarly journals Anionic Polymerization of Vinylsilanes III. Polymerization Behavior of Trimethylvinylsilane

1991 ◽  
Vol 23 (11) ◽  
pp. 1377-1382 ◽  
Author(s):  
Jun-ichi Oku ◽  
Takashi Hasegawa ◽  
Toshio Takeuchi ◽  
Mikio Takaki
Keyword(s):  
Anionic Polymerization ◽  
Polymerization Behavior

Anionic polymerization of N ,N -dialkyl-2-methylenebut-3-enamide: Effect of alkyl substituents on polymerization behavior

2010 ◽  
Vol 48 (17) ◽  
pp. 3714-3721 ◽  
Author(s):  
Katsuhiko Takenaka ◽  
Natsuyo Shibata ◽  
Akihiko Oshikiri ◽  
Masamitsu Miya ◽  
Hiroki Takeshita ◽  
...  
Keyword(s):  
Anionic Polymerization ◽  
Polymerization Behavior

The anionic polymerization of cyanogen

1966 ◽  
Vol 31 (1) ◽  
pp. 243-251 ◽  
Author(s):  
J. Peška ◽  
M. J. Beneš ◽  
O. Wichterle
Keyword(s):  
Anionic Polymerization

Mechanism of the propagation step in the anionic polymerization of styrene

1980 ◽  
Vol 45 (4) ◽  
pp. 1047-1055 ◽  
Author(s):  
Miroslav Kašpar ◽  
Jiří Trekoval
Keyword(s):  
Experimental Data ◽  
Induction Period ◽  
Anionic Polymerization ◽  
Reactive Intermediate ◽  
Coordination Polymerization ◽  
Kinetic Dependence ◽  
Mathematical Solution ◽  
Slow Reaction

The paper is dealing with an investigation of the kinetic dependence of the propagation step in the anionic coordination polymerization of styrene in benzene at 303 K with "living" oligostyryllithium as initiator at the onset of the reaction. A short but distinct induction period was found, indicating a preceding slow reaction leading to the formation of a reactive intermediate, which behaves as the initiator of the reaction. Using results obtained in the first paper of this series, a new mechanism of propagation has been suggested, the mathematical solution of which is correlated with experimental data.

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