Isoprene polymerization with indolide-imine supported rare-earth metal alkyl and amidinate complexes

2008 ◽  
Vol 46 (15) ◽  
pp. 5251-5262 ◽  
Author(s):  
Yi Yang ◽  
Qiaoyi Wang ◽  
Dongmei Cui
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Isoprene Polymerization

Rare‐Earth‐Metal Pentadienyl Half‐Sandwich and Sandwich Tetramethylaluminates–Synthesis, Structure, Reactivity, and Performance in Isoprene Polymerization

2019 ◽  
Vol 25 (18) ◽  
pp. 4821-4832 ◽  
Author(s):  
Damir Barisic ◽  
Dennis A. Buschmann ◽  
David Schneider ◽  
Cäcilia Maichle‐Mössmer ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
And Performance ◽  
Half Sandwich ◽  
Isoprene Polymerization

Rare-earth metal-promoted (double) C–H-bond activation of a lutidinyl-functionalized alkoxy ligand: formation of [ONC] pincer-type ligands and implications for isoprene polymerization

2020 ◽  
Vol 49 (6) ◽  
pp. 2004-2013 ◽  
Author(s):  
Dominic Diether ◽  
Melanie Meermann-Zimmermann ◽  
Karl W. Törnroos ◽  
Cäcilia Maichle-Mössmer ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Bond Activation ◽  
Earth Metal ◽  
Isoprene Polymerization

Steric pressure enforces the formation of dianionic and trianionic pincer-type ligands involving a rare alkylidene moiety in the latter case.

Homoleptic Rare-Earth Metal(III) Tetramethylaluminates: Structural Chemistry, Reactivity, and Performance in Isoprene Polymerization

2007 ◽  
Vol 13 (31) ◽  
pp. 8784-8800 ◽  
Author(s):  
Melanie Zimmermann ◽  
Nils Åge Frøystein ◽  
Andreas Fischbach ◽  
Peter Sirsch ◽  
H. Martin Dietrich ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Structural Chemistry ◽  
And Performance ◽  
Isoprene Polymerization

Rare-earth metal bis(alkyl) complexes bearing pyrrolidinyl-functionalized cyclopentadienyl, indenyl and fluorenyl ligands: synthesis, characterization and the ligand effect on isoprene polymerization

2015 ◽  
Vol 39 (10) ◽  
pp. 7575-7581 ◽  
Author(s):  
Meng Deng ◽  
Shuhui Chi ◽  
Yunjie Luo
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Ligand Effect ◽  
Alkyl Complexes ◽  
Isoprene Polymerization

The ligand effect on isoprene polymerization was investigated using rare-earth metal bis(alkyl) complexes bearing pyrrolidinyl-functionalized cyclopentadienyl, indenyl and fluorenyl ligands.

C–H Bond Activation and Isoprene Polymerization by Rare-Earth-Metal Tetramethylaluminate Complexes Bearing Formamidinato N-Ancillary Ligands

2013 ◽  
Vol 32 (5) ◽  
pp. 1209-1223 ◽  
Author(s):  
Shima Hamidi ◽  
Lars N. Jende ◽  
H. Martin Dietrich ◽  
Cäcilia Maichle-Mössmer ◽  
Karl W. Törnroos ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Bond Activation ◽  
Earth Metal ◽  
Ancillary Ligands ◽  
Isoprene Polymerization

Rare-earth metal alkyl complexes bearing an alkoxy N-heterocyclic carbene ligand: synthesis, characterization, catalysis for isoprene polymerization

2015 ◽  
Vol 39 (10) ◽  
pp. 7682-7687 ◽  
Author(s):  
Shiyu Long ◽  
Baoli Wang ◽  
Hongyan Xie ◽  
Changguang Yao ◽  
Chunji Wu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Alkyl Complexes ◽  
Ligand Synthesis ◽  
Isoprene Polymerization

The new rare-earth metal alkyl complexes bearing alkoxy NHC ligands were prepared, which showed moderate cis-1,4 selectivity for isoprene polymerization.

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