Synthesis of poly(benzyl glutamate-b-styrene) rod-coil block copolymers by dual initiation in one pot

2008 ◽  
Vol 46 (9) ◽  
pp. 3068-3077 ◽  
Author(s):  
Rutger J. I. Knoop ◽  
Gijs J. M. Habraken ◽  
Nicolas Gogibus ◽  
Simone Steig ◽  
Henning Menzel ◽  
...  
Keyword(s):  
Block Copolymers ◽  
One Pot ◽  
Dual Initiation

scholarly journals Precise Synthesis and Thin Film Self-Assembly of PLLA-b-PS Bottlebrush Block Copolymers

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1412
Author(s):  
Eunkyung Ji ◽  
Cian Cummins ◽  
Guillaume Fleury
Keyword(s):  
Thin Film ◽  
Block Copolymers ◽  
Self Assembly ◽  
Ring Opening ◽  
Periodic Structures ◽  
One Pot ◽  
Ordered Structures ◽  
Carbonyl Chloride ◽  
Thin Film Patterning ◽  
Nanoporous Templates

The ability of bottlebrush block copolymers (BBCPs) to self-assemble into ordered large periodic structures could greatly expand the scope of photonic and membrane technologies. In this paper, we describe a two-step synthesis of poly(l-lactide)-b-polystyrene (PLLA-b-PS) BBCPs and their rapid thin-film self-assembly. PLLA chains were grown from exo-5-norbornene-2-methanol via ring-opening polymerization (ROP) of l-lactide to produce norbornene-terminated PLLA. Norbonene-terminated PS was prepared using anionic polymerization followed by a termination reaction with exo-5-norbornene-2-carbonyl chloride. PLLA-b-PS BBCPs were prepared from these two norbornenyl macromonomers by a one-pot sequential ring opening metathesis polymerization (ROMP). PLLA-b-PS BBCPs thin-films exhibited cylindrical and lamellar morphologies depending on the relative block volume fractions, with domain sizes of 46–58 nm and periodicities of 70–102 nm. Additionally, nanoporous templates were produced by the selective etching of PLLA blocks from ordered structures. The findings described in this work provide further insight into the controlled synthesis of BBCPs leading to various possible morphologies for applications requiring large periodicities. Moreover, the rapid thin film patterning strategy demonstrated (>5 min) highlights the advantages of using PLLA-b-PS BBCP materials beyond their linear BCP analogues in terms of both dimensions achievable and reduced processing time.

Amphiphilic Diblock Copolymers of Poly(glycidol) with Biodegradable Polyester/Polycarbonate. Organocatalytic One-Pot ROP and Self-Assembling Property

2021 ◽  
Author(s):  
Tingyu He ◽  
Atsushi Narumi ◽  
Yanqiu Wang ◽  
Liang Xu ◽  
Shin-ichiro Sato ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Diblock Copolymers ◽  
Amphiphilic Block Copolymers ◽  
Synthetic Method ◽  
Biodegradable Polyester ◽  
One Pot ◽  
Self Assembling ◽  
Amphiphilic Diblock Copolymers

A synthetic method for a series of poly(glycidol) (PG)-based amphiphilic block copolymers is presented with an emphasis on the catalyst switch method from an organic superbase (t-Bu-P4) to another with...

scholarly journals One-Pot Synthesis of Block Copolymers by a Combination of Living Cationic and Controlled Radical Polymerization

2019 ◽  
Vol 40 (1) ◽  
pp. 1970001
Author(s):  
Anne-Kristin Trützschler ◽  
Meike N. Leiske ◽  
Maria Strumpf ◽  
Johannes C. Brendel ◽  
Ulrich S. Schubert
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
One Pot ◽  
One Pot Synthesis

Aluminum‐Catalyzed One‐Pot Synthesis of Polyester‐ b ‐Polypeptide Block Copolymers by Ring‐Opening Polymerization

2019 ◽  
Vol 220 (14) ◽  
pp. 1900040 ◽  
Author(s):  
Thibault E. Schmid ◽  
Carine Robert ◽  
Vincent Richard ◽  
Sumesh K. Raman ◽  
Vincent Guérineau ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
One Pot ◽  
One Pot Synthesis

Metal-Free Approach for a One-Pot Construction of Biodegradable Block Copolymers from Epoxides, Phthalic Anhydride, and CO2

2020 ◽  
Vol 8 (48) ◽  
pp. 17860-17867
Author(s):  
Shuxian Ye ◽  
Wenjing Wang ◽  
Jiaxin Liang ◽  
Shuanjin Wang ◽  
Min Xiao ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Phthalic Anhydride ◽  
One Pot ◽  
Metal Free

One-pot synthesis of poly(l-lactide)-b-poly(methyl methacrylate) block copolymers

RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38243-38247 ◽  
Author(s):  
Junzhe Song ◽  
Jinbao Xu ◽  
Stergios Pispas ◽  
Guangzhao Zhang
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
One Pot ◽  
Poly Methyl Methacrylate ◽  
One Pot Synthesis

The combination of ROP and ATRP in a one-pot process with DBU as ATRP ligand and ROP catalyst results in the synthesis of poly(l-lactide)-b-poly(methyl methacrylate) block copolymers.

scholarly journals Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO 2 ‐Based Block Copolymers from Monomer Mixtures

2019 ◽  
Vol 58 (40) ◽  
pp. 14311-14318 ◽  
Author(s):  
Yajun Zhao ◽  
Yong Wang ◽  
Xingping Zhou ◽  
Zhigang Xue ◽  
Xianhong Wang ◽  
...  
Keyword(s):  
Block Copolymers ◽  
One Pot ◽  
One Pot Synthesis ◽  
The One
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