scholarly journals Synthesis of poly(di[methylamine]ethyl methacrylate)-b-poly(cyclohexyl methacrylate)-b-poly(di[methylamine]ethyl methacrylate) amphiphilic triblock copolymers by ATRP: Condensed-phase and solution properties

2007 ◽  
Vol 46 (1) ◽  
pp. 85-92 ◽  
Author(s):  
Alexandra Muñoz-Bonilla ◽  
David M. Haddleton ◽  
María L. Cerrada ◽  
Marta Fernández-García
2006 ◽  
Vol 44 (11) ◽  
pp. 3674-3683 ◽  
Author(s):  
Sami Hietala ◽  
Andreas Nyström ◽  
Heikki Tenhu ◽  
Anders Hult

1975 ◽  
Vol 28 (10) ◽  
pp. 2161 ◽  
Author(s):  
RD Sothman ◽  
JR Urwin

D.s.c. heating curves have been obtained from solutions of a series of well characterized poly-(styrene : isoprene : styrene) triblock copolymers. In the preferential solvent, methylcyclohexane, endotherms and/or exotherms (depending on composition) were observed from all polymers with composition in excess of 10% polystyrene. These phenomena were not observed from solutions of the copolymers in good or poor solvents for both kinds of segments. An explanation is given in terms of gel formation and polymer aggregation.


1977 ◽  
Vol 42 (6) ◽  
pp. 1960-1968 ◽  
Author(s):  
M. Doležalová ◽  
V. Petrus ◽  
M. Bohdanecký

e-Polymers ◽  
2001 ◽  
Vol 1 (1) ◽  
Author(s):  
Kirsten Markgraf ◽  
Volker Abetz

AbstractBlends of microphase separated polystyrene-block-polybutadiene-blockpoly( methacrylic acid) triblock copolymers (SBA) with polystyrene-block-poly(2- vinylpyridine) (SV) or poly(2-vinylpyridine)-block-poly(cyclohexyl methacrylate) (VC) diblock copolymers were prepared and characterized. Attractive segmental interactions through hydrogen bonds between A and V could be monitored by infrared spectroscopy and dynamic mechanical analysis. Common superlattices were obtained by casting from a mixed solution of these block copolymers in tetrahydrofuran and were investigated by transmission electron microscopy. Varying the amount of hydrogen bonding donors via controlled saponification of an SBT triblock copolymer (T: poly(tert-butyl methacrylate)) lead to different superlattices in blends with a VC diblock copolymer.


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