Thermal stability of reversible addition-fragmentation chain transfer/macromolecular architecture design by interchange of xanthates chain-transfer agents

2006 ◽  
Vol 44 (24) ◽  
pp. 6980-6987 ◽  
Author(s):  
Thomas M. Legge ◽  
Andrew T. Slark ◽  
Sébastien Perrier
Keyword(s):  
Thermal Stability ◽  
Chain Transfer ◽  
Architecture Design ◽  
Reversible Addition ◽  
Macromolecular Architecture ◽  
Thermal Stability Of ◽  
Transfer Agents

scholarly journals The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation

2008 ◽  
Vol 73 (8-9) ◽  
pp. 915-921 ◽  
Author(s):  
Lynne Katsikas ◽  
Milena Avramovic ◽  
Betancourt Cortés ◽  
Milos Milovanovic ◽  
Melina Kalagasidis-Krusic ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Double Bonds ◽  
Poly Methyl Methacrylate ◽  
Reversible Addition ◽  
Raft Agent ◽  
Thermal Stability Of

Poly(methyl methacrylate), PMMA, was prepared by reversible addition-fragmentation chain transfer, RAFT, polymerisation using 2-(2-cyanopropyl)-dithiobenzoate, CPDB, as the RAFT agent. The thermal stability of the resulting polymer approached that of anionically prepared PMMA, as determined by thermogravimetry. This was the consequence of the RAFT prepared polymer having no head-to-head links and no chain end double bonds, which are responsible for the relatively low thermal stability of radically prepared PMMA.

Pseudoliving polymerization of vinyl acetate mediated by reversible addition-fragmentation chain-transfer agents

2011 ◽  
Vol 53 (7-8) ◽  
pp. 437-447 ◽  
Author(s):  
E. V. Chernikova ◽  
V. V. Yulusov ◽  
K. O. Mineeva ◽  
V. B. Golubev ◽  
E. S. Garina
Keyword(s):  
Vinyl Acetate ◽  
Chain Transfer ◽  
Reversible Addition ◽  
Transfer Agents

Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization) Using Dithiocarbamates as Chain Transfer Agents

1999 ◽  
Vol 32 (21) ◽  
pp. 6977-6980 ◽  
Author(s):  
Roshan T. A. Mayadunne ◽  
Ezio Rizzardo ◽  
John Chiefari ◽  
Yen Kwong Chong ◽  
Graeme Moad ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Reversible Addition ◽  
Transfer Agents
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