Fundamentals and development of high-efficiency supported catalyst systems for atom transfer radical polymerization

2007 ◽  
Vol 45 (4) ◽  
pp. 553-565 ◽  
Author(s):  
Santiago Faucher ◽  
Shiping Zhu
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
High Efficiency ◽  
Supported Catalyst ◽  
Atom Transfer ◽  
Catalyst Systems

Magnetic Nanoparticle Supported Catalyst for Atom Transfer Radical Polymerization

2006 ◽  
Vol 39 (19) ◽  
pp. 6399-6405 ◽  
Author(s):  
Shijie Ding ◽  
Yangchuan Xing ◽  
Maciej Radosz ◽  
Youqing Shen
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Magnetic Nanoparticle ◽  
Supported Catalyst ◽  
Atom Transfer

scholarly journals Iron Catalysts in Atom Transfer Radical Polymerization

Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1648 ◽  
Author(s):  
Sajjad Dadashi-Silab ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
High Efficiency ◽  
Catalyst Design ◽  
Iron Catalysts ◽  
Atom Transfer ◽  
Controlled Polymerization ◽  
Catalytic Systems ◽  
Functional Monomers ◽  
Styrene Atrp

Catalysts are essential for mediating a controlled polymerization in atom transfer radical polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly efficient, leading to well-controlled polymerization of a variety of functional monomers. In addition to copper, iron-based complexes offer new opportunities in ATRP catalysis to develop environmentally friendly, less toxic, inexpensive, and abundant catalytic systems. Despite the high efficiency of iron catalysts in controlling polymerization of various monomers including methacrylates and styrene, ATRP of acrylate-based monomers by iron catalysts still remains a challenge. In this paper, we review the fundamentals and recent advances of iron-catalyzed ATRP focusing on development of ligands, catalyst design, and techniques used for iron catalysis in ATRP.

Redox Responsive Behavior of Thiol/Disulfide-Functionalized Star Polymers Synthesized via Atom Transfer Radical Polymerization

2010 ◽  
Vol 43 (9) ◽  
pp. 4133-4139 ◽  
Author(s):  
Jun Kamada ◽  
Kaloian Koynov ◽  
Cathrin Corten ◽  
Azhar Juhari ◽  
Jeong Ae Yoon ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Star Polymers ◽  
Atom Transfer ◽  
Redox Responsive ◽  
Responsive Behavior
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