Ultrafast synthesis of poly(methyl acrylate) and poly(methyl acrylate)-b-poly(vinyl chloride)-b-poly(methyl acrylate) by the Cu(0)/tris(2-dimethylaminoethyl)amine-catalyzed living radical polymerization and block copolymerization of methyl acrylate initiated with 1,1-chloroiodoethane and ?,?-Di(iodo)poly(vinyl chloride) in dimethyl sulfoxide

2005 ◽  
Vol 43 (9) ◽  
pp. 1948-1954 ◽  
Author(s):  
Virgil Percec ◽  
Tamaz Guliashvili ◽  
Anatoliy V. Popov
Keyword(s):  
Dimethyl Sulfoxide ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
Block Copolymerization ◽  
Poly Vinyl Chloride

Scale-up of Poly[(Vinyl Chloride)-b-(n-Butyl Acrylate)-b-(Vinyl Chloride)] prepared by Living Radical Polymerization

2006 ◽  
Vol 514-516 ◽  
pp. 975-979 ◽  
Author(s):  
Jorge F.J. Coelho ◽  
Patricia Alves ◽  
Joana Monteiro ◽  
M. Margarida C.A. Castro ◽  
Mariana Abreu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Scale Up ◽  
Living Radical Polymerization ◽  
Poly Vinyl Chloride

Vinyl Chloride (VCM) based copolymers were synthesised by using Living Radical Polymerization. The obtained materials were characterized by determining their molecular weight, glass transition temperature and mechanical properties after processing in industrial equipments. Their chemical composition was evaluated by using NMR.

Sign in / Sign up

Export Citation Format

Share Document