Synthesis and characterization of telechelic polymethacrylates via RAFT polymerization

2005 ◽  
Vol 43 (5) ◽  
pp. 959-973 ◽  
Author(s):  
Vincent Lima ◽  
Xulin Jiang ◽  
Jos� Brokken-Zijp ◽  
Peter J. Schoenmakers ◽  
Bert Klumperman ◽  
...  
Keyword(s):  
Raft Polymerization ◽  
Synthesis And Characterization

Synthesis of Novel Triazole-Containing Phosphonate Polymers

2015 ◽  
Vol 68 (4) ◽  
pp. 680 ◽  
Author(s):  
Ciarán Dolan ◽  
Briar Naysmith ◽  
Simon F. R. Hinkley ◽  
Ian M. Sims ◽  
Margaret A. Brimble ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Click Reaction ◽  
Raft Polymerization ◽  
Ethyl Acrylate ◽  
Polymer Chemistry ◽  
Synthesis And Characterization ◽  
Reversible Addition

The objective of this research was to develop novel phosphonate-containing polymers as they remain a relatively under researched area of polymer chemistry. Herein, we report the synthesis and characterization of 2-(1-(2-(diethoxyphosphoryl)ethyl)-1H-1,2,3-triazol-4-yl)ethyl acrylate (M1) and diethyl (2-(4-(2-acrylamidoethyl)-1H-1,2,3-triazol-1-yl)ethyl)phosphonate (M2) monomers using the copper-catalyzed azide–alkyne cycloaddition (CuAAC) ‘click’ reaction, and their subsequent polymerization via both uncontrolled and reversible addition–fragmentation chain transfer (RAFT) polymerization techniques yielding phosphonate polymers (P1–P4).

Synthesis of Novel Triazole-Containing Phosphonate Polymers

2020 ◽  
Author(s):  
C Dolan ◽  
B Naysmith ◽  
Simon Hinkley ◽  
Ian Sims ◽  
MA Brimble ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Click Reaction ◽  
Raft Polymerization ◽  
Ethyl Acrylate ◽  
Polymer Chemistry ◽  
Synthesis And Characterization ◽  
Reversible Addition

© 2015 CSIRO. The objective of this research was to develop novel phosphonate-containing polymers as they remain a relatively under researched area of polymer chemistry. Herein, we report the synthesis and characterization of 2-(1-(2-(diethoxyphosphoryl)ethyl)-1H-1,2,3-triazol-4-yl)ethyl acrylate (M1) and diethyl (2-(4-(2-acrylamidoethyl)-1H-1,2,3-triazol-1-yl)ethyl)phosphonate (M2) monomers using the copper-catalyzed azide-alkyne cycloaddition (CuAAC) 'click' reaction, and their subsequent polymerization via both uncontrolled and reversible addition-fragmentation chain transfer (RAFT) polymerization techniques yielding phosphonate polymers (P1-P4).

Synthesis and characterization of novel amphiphilic biocompatible block-copolymers of poly(N-isopropylacrylamide)-b-poly(l-phenylalanine methyl ester) by RAFT polymerization

Polymer ◽  
2020 ◽  
Vol 203 ◽  
pp. 122760 ◽  
Author(s):  
Chandra Sekhar Biswas ◽  
Arpan Biswas ◽  
Massimillano Galluzzi ◽  
Mehdihasan I. Shekh ◽  
Qiao Wang ◽  
...  
Keyword(s):  
Methyl Ester ◽  
Block Copolymers ◽  
Raft Polymerization ◽  
Synthesis And Characterization ◽  
Phenylalanine Methyl Ester
Sign in / Sign up

Export Citation Format

Share Document