Dependence of the kinetics of the anionic polymerization of methyl methacrylate on the concentration in active centers

Fran�ois Lavaud; Michel Fontanille; Yves Gnanou

doi:10.1002/pola.20331

Dependence of the kinetics of the anionic polymerization of methyl methacrylate on the concentration in active centers

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.20331 ◽

2004 ◽

Vol 42 (19) ◽

pp. 4964-4975 ◽

Cited By ~ 1

Author(s):

Fran�ois Lavaud ◽

Michel Fontanille ◽

Yves Gnanou

Keyword(s):

Methyl Methacrylate ◽

Anionic Polymerization ◽

Active Centers ◽

Kinetics Of

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The effect of TMEDA on the kinetics of the anionic polymerization of methyl methacrylate in tetrahydrofuran using lithium as counterion

Macromolecular Chemistry and Physics ◽

10.1002/1521-3935(20000901)201:14<1901::aid-macp1901>3.0.co;2-j ◽

2000 ◽

Vol 201 (14) ◽

pp. 1901-1911 ◽

Cited By ~ 14

Author(s):

D. Baskaran ◽

Axel H. E. Müller ◽

S. Sivaram

Keyword(s):

Methyl Methacrylate ◽

Anionic Polymerization ◽

Kinetics Of

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Effect of Lithium Perchlorate on the Kinetics of the Anionic Polymerization of Methyl Methacrylate in Tetrahydrofuran

Macromolecules ◽

10.1021/ma961920y ◽

1999 ◽

Vol 32 (5) ◽

pp. 1356-1361 ◽

Cited By ~ 16

Author(s):

D. Baskaran ◽

Axel H. E. Müller ◽

S. Sivaram

Keyword(s):

Methyl Methacrylate ◽

Anionic Polymerization ◽

Lithium Perchlorate ◽

Kinetics Of

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Effect of LiClO4 and LiCl Additives on the Kinetics of Anionic Polymerization of Methyl Methacrylate in Toluene-Tetrahydrofuran Mixed Solvent

Macromolecular Chemistry and Physics ◽

10.1002/macp.200350016 ◽

2003 ◽

Vol 204 (12) ◽

pp. 1567-1575 ◽

Cited By ~ 5

Author(s):

Mahua G. Dhara ◽

Durairaj Baskaran ◽

Swaminathan Sivaram

Keyword(s):

Methyl Methacrylate ◽

Anionic Polymerization ◽

Mixed Solvent ◽

Kinetics Of

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Density Functional Theory Study on the Aggregation and Dissociation Behavior of Lithium Chloride in THF and Its Interaction with the Active Centers of the Anionic Polymerization of Methyl Methacrylate and Styrene

Macromolecules ◽

10.1021/ma9921549 ◽

2000 ◽

Vol 33 (15) ◽

pp. 5686-5692 ◽

Cited By ~ 25

Author(s):

Alexander V. Yakimansky ◽

Axel H. E. Müller ◽

Marcel Van Beylen

Keyword(s):

Density Functional Theory ◽

Methyl Methacrylate ◽

Lithium Chloride ◽

Anionic Polymerization ◽

Density Functional ◽

Density Functional Theory Study ◽

Active Centers ◽

Functional Theory

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Cross-Aggregation of Active Centers in a Model Anionic Polymerization System. The Kinetics of the Reactions of Silanolates with Cyclic and Linear Polysiloxanes

Macromolecules ◽

10.1021/ma60062a013 ◽

1978 ◽

Vol 11 (2) ◽

pp. 347-356 ◽

Cited By ~ 13

Author(s):

Mieczyslaw Mazurek ◽

Julian Chojnowski

Keyword(s):

Anionic Polymerization ◽

Active Centers ◽

Polymerization System ◽

Kinetics Of

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Anionic polymerization initiated by lamellar compounds of LiC12: 1. Kinetics of the polymerization of styrene and isoprene — initiator efficiency

Polymer ◽

10.1016/0032-3861(81)90082-3 ◽

1981 ◽

Vol 22 (1) ◽

pp. 95-100 ◽

Cited By ~ 7

Author(s):

E. Loria ◽

G. Merle ◽

J.P. Pascault ◽

I.B. Rashkov

Keyword(s):

Anionic Polymerization ◽

Initiator Efficiency ◽

Kinetics Of

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The Kinetics of Methyl Methacrylate Miniemulsion Polymerization Characterized through a Fluorescence Method

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.178-181.609 ◽

2012 ◽

Vol 178-181 ◽

pp. 609-612

Author(s):

Hai Ke Feng ◽

Hua Yu Qiu ◽

Li Yuan Ding ◽

Cun Jin Xu

Keyword(s):

Methyl Methacrylate ◽

Anionic Surfactant ◽

Sodium Dodecyl Sulphate ◽

Sodium Dodecyl ◽

Miniemulsion Polymerization ◽

Time Measurement ◽

Fluorescence Method ◽

Real Time Measurement ◽

Measurement Results ◽

Kinetics Of

In this paper, we followed the kinetics of methyl methacrylate (MMA) through a novel fluorescence method. The real-time measurement results show that in the regime of very low monomer contents, such as a solution containing 0.1 wt% of MMA with respect to water and with the anionic surfactant of sodium dodecyl sulphate (SDS), the kinetic of the miniemulsion could be followed by this embed fluorescence method. The processes of changing from emulsion to miniemulsion with different amount of surfactant and cosurfactant also have been monitored.

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Kinetics of the Anionic Polymerization of Buta-1,3-diene Considering Different Reactivities of the cis, trans and vinyl Structural Units

Macromolecular Reaction Engineering ◽

10.1002/mren.200800008 ◽

2008 ◽

Vol 2 (5) ◽

pp. 436-451 ◽

Cited By ~ 3

Author(s):

José A. Tenorio López ◽

Juan J. Benvenuta Tapia ◽

Celestino Montiel Maldonado ◽

Leonardo Ríos Guerrero

Keyword(s):

Anionic Polymerization ◽

Structural Units ◽

Kinetics Of

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Anionic Polymerization of Acrylic Monomers. 19. Effect of Various Types of Ligands Other Than Lithium Chloride on the Stereochemistry of Anionic Polymerization of Methyl Methacrylate

Macromolecules ◽

10.1021/ma00096a009 ◽

1994 ◽

Vol 27 (18) ◽

pp. 4902-4907 ◽

Cited By ~ 11

Author(s):

Jin-Shan Wang ◽

Robert Jerome ◽

Philippe Teyssie

Keyword(s):

Methyl Methacrylate ◽

Lithium Chloride ◽

Anionic Polymerization ◽

Acrylic Monomers

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Studies of the mechanism and kinetics of plasma-initiated polymerization of methyl methacrylate

Macromolecules ◽

10.1021/ma50002a024 ◽

1981 ◽

Vol 14 (1) ◽

pp. 118-124 ◽

Cited By ~ 43

Author(s):

D. R. Johnson ◽

Y. Osada ◽

A. T. Bell ◽

M. Shen

Keyword(s):

Methyl Methacrylate ◽

Mechanism And Kinetics ◽

Kinetics Of

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