Synthesis of core-shell poly(divinylbenzene) microspheres via reversible addition fragmentation chain transfer graft polymerization of styrene

2004 ◽  
Vol 42 (20) ◽  
pp. 5067-5076 ◽  
Author(s):  
Leonie Barner ◽  
Chao'En Li ◽  
Xiaojuan Hao ◽  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik ◽  
...  
Keyword(s):  
Graft Polymerization ◽  
Chain Transfer ◽  
Core Shell ◽  
Reversible Addition

Toughening of an epoxy thermoset with poly[styrene-alt-(maleic acid)]-block-polystyrene-block-poly(n-butyl acrylate) reactive core–shell particles

RSC Advances ◽  
2016 ◽  
Vol 6 (42) ◽  
pp. 35621-35627 ◽  
Author(s):  
Ren He ◽  
Xiaoli Zhan ◽  
Qinghua Zhang ◽  
Fengqiu Chen
Keyword(s):  
Emulsion Polymerization ◽  
Maleic Acid ◽  
Butyl Acrylate ◽  
Chain Transfer ◽  
Core Shell ◽  
Reversible Addition ◽  
Raft Agent ◽  
Shell Particles

Reactive core–shell particles for epoxy toughening were synthesized via reversible addition–fragmentation chain transfer emulsion polymerization mediated by an amphiphilic macro-RAFT agent followed by core-crosslinking to increase stability.

Preparation of core–shell attapulgite particles by redox-initiated surface reversible addition–fragmentation chain transfer polymerization via a “graft from” approach

RSC Advances ◽  
2016 ◽  
Vol 6 (17) ◽  
pp. 14120-14127 ◽  
Author(s):  
Haicun Yang ◽  
Sheng Xue ◽  
Ji Pan ◽  
Fanghong Gong ◽  
Hongting Pu
Keyword(s):  
Polymethyl Methacrylate ◽  
Chain Transfer ◽  
Core Shell ◽  
Redox Initiation ◽  
Initiation System ◽  
System P ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

Polymethyl methacrylate layer was grown uniformly from attapulgite by using surface-initiated reversible addition–fragmentation chain transfer polymerization via redox initiation system.

RAFT Graft Polymerization of 2-(Dimethylaminoethyl) Methacrylate onto Cellulose Fibre

2006 ◽  
Vol 59 (10) ◽  
pp. 737 ◽  
Author(s):  
Debashish Roy ◽  
James T. Guthrie ◽  
Sébastien Perrier
Keyword(s):  
Graft Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Cellulose Fibre ◽  
Monomer Conversion ◽  
Living System ◽  
Degree Of Polymerization ◽  
Polymerization Time ◽  
Grafted Polymer ◽  
Reversible Addition

Poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) was grafted from cellulose by reversible addition–fragmentation chain transfer (RAFT) polymerization. The use of a free chain transfer agent in solution allowed for a better control over graft ratio, chain length of grafted polymer, monomer conversion, and homopolymer formation in solution. An increase in polymerization time or degree of polymerization led to an increase in graft ratio, as expected from a living system.

Core–shell structured poly(vinylidene fluoride)-grafted-BaTiO3 nanocomposites prepared via reversible addition–fragmentation chain transfer (RAFT) polymerization of VDF for high energy storage capacitors

2019 ◽  
Vol 10 (7) ◽  
pp. 891-904 ◽  
Author(s):  
Fatima Ezzahra Bouharras ◽  
Mustapha Raihane ◽  
Gilles Silly ◽  
Cedric Totee ◽  
Bruno Ameduri
Keyword(s):  
Energy Storage ◽  
Chain Transfer ◽  
Vinylidene Fluoride ◽  
Raft Polymerization ◽  
High Energy ◽  
Core Shell ◽  
Reversible Addition ◽  
Poly Vinylidene Fluoride ◽  
High Energy Storage

Core–shell structured PVDF-g-BaTiO3 nanocomposites were prepared by surface-initiated RAFT of VDF from BaTiO3 nanoparticles.

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