Reversible addition-fragmentation chain transfer polymerization of glycidyl methacrylate with 2-cyanoprop-2-yl 1-dithionaphthalate as a chain-transfer agent

2004 ◽  
Vol 42 (10) ◽  
pp. 2558-2565 ◽  
Author(s):  
Jian Zhu ◽  
Di Zhou ◽  
Xiulin Zhu ◽  
Gaojian Chen
Keyword(s):  
Glycidyl Methacrylate ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Reversible Addition ◽  
A Chain ◽  
Chain Transfer Polymerization

scholarly journals Synthesis of bottlebrush polymers via transfer-to and grafting-through approaches using a RAFT chain transfer agent with a ROMP-active Z-group

2015 ◽  
Vol 6 (31) ◽  
pp. 5643-5652 ◽  
Author(s):  
Scott C. Radzinski ◽  
Jeffrey C. Foster ◽  
John B. Matson
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Multiple Strategies ◽  
Reversible Addition ◽  
Grafting Through ◽  
Chain Transfer Polymerization

A novel dithiocarbamate chain transfer agent for reversible addition–fragmentation chain transfer polymerization with a directly polymerizable Z-group was synthesized and used to make bottlebrush polymers via multiple strategies.

Copolymerization of Glycidyl Methacrylate and 1,1,1,3,3,3-Hexafluoroisopropyl Acrylate

2021 ◽  
Vol 899 ◽  
pp. 387-391
Author(s):  
Alexandra O. Grigoreva ◽  
Kseniia Tarankova ◽  
Sergey D. Zaitsev
Keyword(s):  
Glycidyl Methacrylate ◽  
Molar Mass ◽  
Chain Transfer ◽  
Good Control ◽  
Chain Transfer Agent ◽  
Polymeric Chain ◽  
Reactivity Ratios ◽  
Reversible Addition

The copolymerization of 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) and glycidyl methacrylate via reversible addition-fragmentation chain transfer (RAFT) process was investigated. 2-cyano-2-propyl dodecyl trithiocarbonate (CPDT) was used as chain transfer agent. It is turned out that CPDT and polymeric chain transfer agent obtained based on HFIPA and CPDT provide a good control over molar mass characteristic of copolymers (Đ = 1.05). Reactivity ratios were found to be r1(GMA) = 1.57 and r2(HFIPA) = 0.05 by Fineman–Ross model.

Novel Amide-Based Chain Transfer Agent for Reversible Addition Fragmentation Chain Transfer Polymerization

2005 ◽  
Vol 38 (4) ◽  
pp. 1057-1060 ◽  
Author(s):  
Pittaya Takolpuckdee ◽  
Craig A. Mars ◽  
Sébastien Perrier ◽  
Stephen J. Archibald
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

Scandium-Catalyzed Syndiospecific Chain-Transfer Polymerization of Styrene Using Anisoles as a Chain Transfer Agent

2016 ◽  
Vol 49 (7) ◽  
pp. 2458-2466 ◽  
Author(s):  
Atsushi Yamamoto ◽  
Masayoshi Nishiura ◽  
Juzo Oyamada ◽  
Hiroyuki Koshino ◽  
Zhaomin Hou
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
A Chain ◽  
Chain Transfer Polymerization
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