Synthesis and spectroscopic characterization of symmetrical isoprene-methyl methacrylate diblock copolymers bearing different anthracene derivatives at the junctions

2003 ◽  
Vol 41 (9) ◽  
pp. 1225-1236 ◽  
Author(s):  
Jian Yang ◽  
Jianping Lu ◽  
Mitchell A. Winnik
Keyword(s):  
Methyl Methacrylate ◽  
Diblock Copolymers ◽  
Spectroscopic Characterization ◽  
Anthracene Derivatives

Preparation and vibrational spectroscopic characterization of copolymers of 2,3-dimethylbutadiene and methyl methacrylate

1993 ◽  
Vol 24 (8) ◽  
pp. 495-500 ◽  
Author(s):  
H. G. M. Edwards ◽  
A. F. Johnson ◽  
I. R. Lewis ◽  
N. J. Ward ◽  
S. Wheelwright
Keyword(s):  
Methyl Methacrylate ◽  
Spectroscopic Characterization

scholarly journals Spectroscopic characterization of photoaccumulated radical anions: a litmus test to evaluate the efficiency of photoinduced electron transfer (PET) processes

2013 ◽  
Vol 9 ◽  
pp. 800-808 ◽  
Author(s):  
Maurizio Fagnoni ◽  
Stefano Protti ◽  
Davide Ravelli ◽  
Angelo Albini
Keyword(s):  
Electron Transfer ◽  
Spectroscopic Characterization ◽  
Secondary Amines ◽  
Radical Anions ◽  
Radical Intermediates ◽  
Ipso Substitution ◽  
Back Electron Transfer ◽  
Anthracene Derivatives ◽  
Litmus Test

Steady-state irradiation in neat acetonitrile of some aromatic nitriles, imides and esters (10−5–10−3 M solution) in the presence of tertiary amines allowed the accumulation of the corresponding radical anions, up to quantitative yield for polysubstituted benzenes and partially with naphthalene and anthracene derivatives. The condition for such an accumulation was that the donor radical cation underwent further evolution that precluded back electron transfer and any chemical reaction with the radical anion. In fact, no accumulation occurred with 1,4-diazabicyclo[2.2.2]octane (DABCO), for which this condition is not possible. The radical anions were produced from benzene polyesters too, but decomposition began early. Ipso substitution was one of the paths with secondary amines and the only reaction with tetrabutylstannane. The results fully support the previously proposed mechanism for electron transfer (ET) mediated photochemical alkylation of aromatic acceptors via radical ions and radical intermediates.

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