Kinetics of polymerization of acrylonitrile initiated by acidic permanganate/thioacetamide redox system

1981 ◽  
Vol 19 (11) ◽  
pp. 2759-2764 ◽  
Author(s):  
Rajani K. Samal ◽  
M. C. Nayak ◽  
G. V. Suryanarayan ◽  
G. Panda ◽  
D. P. Das
Keyword(s):  
Redox System ◽  
Kinetics Of Polymerization ◽  
Kinetics Of

Kinetics of Polymerization of Methyl Methacrylate Initiated by the Redox System Mn3+/Crotonic Acid

1981 ◽  
Vol 15 (8) ◽  
pp. 1461-1471
Author(s):  
Rajani K. Samal ◽  
Padma L. Nayak ◽  
Mohan C. Nayak ◽  
Akshaya K. Dhal ◽  
Purendra C. Dash ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Redox System ◽  
Crotonic Acid ◽  
Kinetics Of Polymerization ◽  
Kinetics Of

Kinetics of polymerization of N,N-methylenebisacrylamide initiated by KMnO4-H2C2O4 redox system

1982 ◽  
Vol 18 (6) ◽  
pp. 531-534 ◽  
Author(s):  
A. Gopalan ◽  
P. Venuvanalingam ◽  
S.P. Manickam ◽  
K. Venkatarao ◽  
N.R. Subbaratnam
Keyword(s):  
Redox System ◽  
Kinetics Of Polymerization ◽  
Kinetics Of

scholarly journals Kinetics of Vinyl Polymerization of Methyl Methacrylate Initiated by Ce(IV)-Vanillin Redox System

2012 ◽  
Vol 9 (1) ◽  
pp. 430-434
Author(s):  
M. Palanivelu ◽  
K. E. N. Nalla Mohamed ◽  
T. Hidayathulla Khan ◽  
M. Prem Nawaz
Keyword(s):  
Sulfuric Acid ◽  
Methyl Methacrylate ◽  
Kinetic Scheme ◽  
Redox System ◽  
Kinetics Of Polymerization ◽  
Rate Of Polymerization ◽  
Reaction Orders ◽  
Higher Temperature ◽  
Increasing Temperature ◽  
Kinetics Of

The kinetics of polymerization of methyl methacrylate initiated by Ce(IV)-Vanillin redox system was studied in aqueous solution of sulfuric acid at 40°C. The rate of polymerization (Rp) and the reaction orders with respect to monomer, initiator and ligand have been determined and found to be 1.5, 0.5 and 0.5 respectively. The effect of concentration of sulfuric acid on the polymerization was also studied. The rate of polymerization was found to increase with increasing temperature 30–60°C and decreases at higher temperature (>60°C). The overall activation energy (Ea) was found to be 36.7 kJ/mol. A suitable kinetic scheme has been proposed.

Kinetics of polymerization initiated by Mn3–substrate redox system. I

1979 ◽  
Vol 17 (12) ◽  
pp. 4099-4105 ◽  
Author(s):  
P. Elayaperumal ◽  
T. Balakrishnan ◽  
M. Santappa ◽  
R. W. Lenz
Keyword(s):  
Redox System ◽  
Kinetics Of Polymerization ◽  
Kinetics Of

Kinetics of polymerization of acrylonitrile initiated by the Mn3-thioacetamide redox system

1980 ◽  
Vol 18 (6) ◽  
pp. 2001-2010 ◽  
Author(s):  
Rajani K. Samal ◽  
Padma L. Nayak ◽  
Mohan C. Nayak ◽  
Akshaya K. Dhal
Keyword(s):  
Redox System ◽  
Kinetics Of Polymerization ◽  
Kinetics Of
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