Crystallization kinetics of polymer–diluent mixtures. Influence of benzophenone on the spherulitic growth rate of isotactic polystyrene

1968 ◽  
Vol 6 (5) ◽  
pp. 885-894 ◽  
Author(s):  
J. Boon ◽  
J. M. Azcue
Keyword(s):  
Growth Rate ◽  
Crystallization Kinetics ◽  
Isotactic Polystyrene ◽  
Spherulitic Growth ◽  
Spherulitic Growth Rate ◽  
Kinetics Of

Study on the Crystallization Kinetics of Polymer Thin Films

2012 ◽  
Vol 466-467 ◽  
pp. 102-105
Author(s):  
Yi Jin Ren
Keyword(s):  
Thin Film ◽  
Growth Rate ◽  
Film Thickness ◽  
Crystallization Kinetics ◽  
Crystallization Time ◽  
Crystal Thickness ◽  
Polymer Thin Film ◽  
Crystal Growth Mechanism ◽  
The Relationship ◽  
Kinetics Of

The crystallization kinetics of polymer thin film has a great difference from that in the bulk. Generally, the growth rate of the crystal confined in thin film reduces with decreasing film thickness, which is believed that the interaction between chains and substrate is responsible for the decrease of the growth rate. In addition, the ratio of film thickness over crystal thickness is also a key parameter in determining the growth rate. The relationship between the crystal lateral size and the crystallization time also dominates the crystal growth mechanism in polymer thin film.

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