Dielectric relaxation process below the glass transition in atactic polystyrene

1968 ◽  
Vol 6 (10) ◽  
pp. 687-689 ◽  
Author(s):  
V. Adamec
Keyword(s):  
Glass Transition ◽  
Dielectric Relaxation ◽  
Relaxation Process ◽  
Dielectric Relaxation Process ◽  
Atactic Polystyrene

scholarly journals PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix

2021 ◽  
Vol 96 ◽  
pp. 107093
Author(s):  
Vera P. Pavlović ◽  
Dragana Tošić ◽  
Radovan Dojčilović ◽  
Duško Dudić ◽  
Miroslav D. Dramićanin ◽  
...  
Keyword(s):  
Dielectric Relaxation ◽  
Relaxation Process ◽  
Polymer Matrix ◽  
Dielectric Relaxation Process ◽  
Ferroelectric Polymer

scholarly journals Molecular Association of Tetramethylurea and Chlorobenzene Molecules in Microwave Frequency Range

2010 ◽  
Vol 65 (10) ◽  
pp. 854-858
Author(s):  
Vimal Sharma ◽  
Nagesh Thakur
Keyword(s):  
Relaxation Time ◽  
Dielectric Relaxation ◽  
Viscous Flow ◽  
Relaxation Process ◽  
Binary Mixtures ◽  
Variation Method ◽  
Dielectric Relaxation Time ◽  
Flow Process ◽  
Dielectric Relaxation Process ◽  
Energy Parameters

The dielectric constant ε´ and dielectric loss ε´´ of the binary mixtures of tetramethylurea (TMU) and chlorobenzene (CB) have been calculated at 9.883 GHz by using standard standing microwave techniques. Gopalakrishna’s single frequency concentration variation method has been used to calculate dipole moment μ and dielectric relaxation time τ for different mole fractions of TMU in the binary mixture at different temperatures of 25 °C, 30 °C, 35 °C, and 40 °C. The variation of dielectric relaxation time with the mole fraction of TMU in the whole concentration range of the binary mixtures was found to be non-monotonic. The solute-solute and solute-solvent type of molecular associations may be proposed based upon above observations. Using Eyring rate equations the energy parameters ΔH, ΔF, and ΔS for the dielectric relaxation process and the viscous flow process have been calculated at the given temperatures. It is found from the comparison of energy parameters that, just like the viscous flow process, the dielectric relaxation process can also be treated as a rate process.

Temperature and voltage stress dependent dielectric relaxation process of the doped Ba0.67Sr0.33TiO3 ceramics

2013 ◽  
Vol 103 (11) ◽  
pp. 112908
Author(s):  
Shiguang Yan ◽  
Chaoliang Mao ◽  
Genshui Wang ◽  
Chunhua Yao ◽  
Fei Cao ◽  
...  
Keyword(s):  
Dielectric Relaxation ◽  
Relaxation Process ◽  
Dielectric Relaxation Process ◽  
Voltage Stress ◽  
Stress Dependent

scholarly journals Dielectric and Conduction Processes and Behaviours in Ni0.3Zn0.7Fe2O4

2016 ◽  
Vol 846 ◽  
pp. 311-317
Author(s):  
Mohd Noor Mat ◽  
M.K. Halimah ◽  
Wan Mohd Daud Wan Yusoff ◽  
H. Mansor ◽  
H. Nizam ◽  
...  
Keyword(s):  
Activation Energy ◽  
Zinc Oxide ◽  
Iron Oxide ◽  
Dielectric Properties ◽  
Dielectric Relaxation ◽  
Relaxation Process ◽  
Peak Frequency ◽  
Frequency Range ◽  
Dielectric Relaxation Process ◽  
Frequency Relaxation

Dielectric relaxation and conductivity of Ni0.3Zn0.7Fe2O4 (NZF) were studied in the frequency range between 0.01 Hz to 3 MHz and temperature range within 313 K to 473 K. The sample was prepared by mixing Zinc Oxide, Nickel Oxide and Iron Oxide and sintered at 1573 K for 10 hours long. Dielectric properties were studied using Novo Control Dielectric Spectrometer. Dielectric relaxation and conductivity phenomena were discussed using an empirical model to key out the dielectric relaxation process. Analyze peak frequency relaxation process consist of four slopes to explain the dielectric relaxation process. The conductivity of the sample indicates an activated process and activation energy of dc conductivity is 0.44 ± 0.01 eV.

scholarly journals Dielectric Relaxation of Mixtures of N-Methylacetamide and N,N-Dimethylformamide Solved in Benzene Using Microwave Absorption Data

2006 ◽  
Vol 61 (3-4) ◽  
pp. 197-204
Author(s):  
Raman Kumar ◽  
V. S. Rangra ◽  
D. R. Sharma ◽  
N. Thakur ◽  
N. S. Negi
Keyword(s):  
Dielectric Relaxation ◽  
Viscous Flow ◽  
Relaxation Process ◽  
Dipole Moments ◽  
Relaxation Times ◽  
Single Frequency ◽  
Absorption Data ◽  
Dielectric Relaxation Process ◽  
Energy Parameters ◽  
Microwave Techniques

The dielectric relaxation times τ and dipole moments μ of N-methylacetamide (NMA) mixed with N,N-dimethylformamide (DMF) in benzene solutions have been obtained using standard standing wave microwave techniques and Gopala Krishna’s single frequency (9.90 GHz) concentration variational method at 25, 30, 35, and 40 ◦C. The energy parameters (ΔHε , ΔFε , ΔSε ) for the dielectric relaxation process of mixtures with equal amounts of NMA and DMF have been calculated and compared with the corresponding energy parameters (ΔHη , ΔFη , ΔSη ) for the viscous flow. On the basis of the observations it is found that the dielectric relaxation process can be treated as a rate process like the viscous flow. Solute-solute and solute-solvent types of the molecular associations have been predicted

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