Organophosphorus herbicides and plant growth regulators part 1. Synthesis and protonation behaviour of glyphosate and related compounds

1990 ◽  
Vol 3 (4) ◽  
pp. 248-254 ◽  
Author(s):  
M. A. Dhansay ◽  
P. W. Linder ◽  
R. G. Torrington ◽  
T. A. Modro
1974 ◽  
Vol 27 (9) ◽  
pp. 1985 ◽  
Author(s):  
LN Mander ◽  
JV Turner ◽  
BG Coombe

Cuminic acid (9) was converted by reductive methylation into 1,2,3,6-tetrahydro-4-isopropyl-1- methylbenzoic acid (12). Acid-catalysed cyclization of the diazomethyl ketone (8) derived from (12), followed by hydrogenation, gave the bicyclo[3,2,l]octanone derivative (7), which was then converted through the allylic bromide mixture of (18) and (19) into the p-toluenesulphonyldithiocarbazone (21) and the allylic ammonium bromide (25). The [2,3]-sigmatropic rearrangement of the dithio- carbene derived from (21) and the ylid derived from (25) afforded the dithioester (22) and pyrrolidine (26), respectively, from which the alcohol (24), aldehydes (27) and (28), and acids (5) and (6) were prepared. Bioassay of (5), (6), (27) and (28) indicated gibberellin-like properties for all these compounds with potency comparable with that of helminthosporic acid (2).


1970 ◽  
Vol 18 (2) ◽  
pp. 243-248 ◽  
Author(s):  
TOSHIHIKO OKAMOTO ◽  
YO ISOGAI ◽  
TORU KOIZUMI ◽  
TAKENORI NISHINO ◽  
YAEKO SATOH

Sign in / Sign up

Export Citation Format

Share Document